Zn22Al4Ag ALLOY MICROWIRES CASTING TO RAPID SOLIDIFICATION PROCESS BY ROTATING DRUM

In this work, the Zn22Al4Ag alloy was synthesized by melting in a muffle furnace.The alloy obtained was characterized by Scanning Electron Microscopy Energy Dispersive Spectroscopy and was analyzed by the X-Ray Diffraction technique, where the crystallinity of the material was verified before and after being processed. Likewise, the Differential Scanning Calorimetry technique was used to obtain the temperatures where phase transformations occurin the alloy. These results were fed to the Termocalc®, software to numerically obtain the phase diagram of the alloy. Subsequently, a section of the ingot was taken to the rapid solidification process by rotating drum. The process variables were manipulated: jet stability, nozzle diameter, distance from the nozzle surface to the cooling medium, the delay time of the molten material in the crucible, speed of the rotating drum and jet angle, until obtaining a microwire with a diameter of ~ 160µm. Finally, it was determined that inadequate control of these parameters can result in powders, flakes or blockage of the crucible outlet. Potentially uses within the micro and nanoworld as an analogy to structural elements and electrical conductors, in addition to its current use as a coating anti-corrosive. Key Words: ZnAlAg alloy, Melt spinning process, Microwire, DSC analysis, Thermodynamic simulation

Exergy, Exergoeconomic, Exergoenvironmental, Emergy-based Assessment and Advanced Exergy-based Analysis of an Integrated Solar Combined Cycle Power Plant

The high amount of solar energy as clean and sustainable energy has increased awareness in solar energy concentration, especially in integrated concepts. One of the best and promising hybrid configurations for converting solar energy into power is an integrated solar combined cycle system (ISCCS). In this study, conventional and advanced analysis tools for the ISCCS located in Yazd (Iran) have been investigated. In this paper, thermodynamic simulation, exergy, exergoeconomic, and exergoenvironmental analysis based on Life Cycle Assessment (LCA) have been performed. In addition, an emergy-based concept, including emergoeconomic and emergoenvironmental assessment, has been performed. In-depth analysis of exergy, exergoeconomic, and exergoenvironmental modelling, advanced exergy analysis based on endogenous/exogenous and avoidable/unavoidable parts have been done. In this regard, MATLAB code has been developed for thermodynamic simulation, exergy, exergoeconomic, exergoenvironment, emergoeconomic and emergoenvironment analysis. Furthermore, THERMOFLEX (commercial software) applied for thermodynamic simulation and verification. The Sankey diagram based on each analysis tool has been constructed. Furthermore, the priority of improvement based on each analysis has been identified. The thermal efficiency and net power generation of ISCCS are 48.25% and 419600 kW, respectively. It was obsereved that in most equipment, less than 10% of exergy destruction and cost and environmental impact rates were avoidable/endogenous.

Effect of Magnesium on the Hydrophobicity of Sphalerite

The use of untreated recycled water has negative effects in the flotation of zinc sulfide ores due to the presence of dissolved species, such as magnesium and calcium. Although it has been found that magnesium is a more potent depressant than calcium, it has not been investigated in this role or for the effect of adding sodium carbonate. The results of an investigation to evaluate the effect of magnesium on the hydrophobicity of Cu-activated sphalerite conditioned with Sodium Isopropyl Xanthate (SIPX) are presented. Zeta potential of natural and Cu-activated sphalerite as a function of the conditioning pH and Cu(II) concentration, respectively, was first evaluated. Later, the effect of pH and presence of magnesium on the contact angle of Cu-activated sphalerite conditioned with SIPX was studied; it was also evaluated the effect of sodium carbonate to counteract the effect of magnesium. Cu-activation enhances the zeta potential of sphalerite up to a concentration of 5 mg/L. Contact angle tests, thermodynamic simulation, and surface analysis showed that magnesium hydroxide precipitates on the sphalerite surface at pH 9.6, decreasing its hydrophobicity. Addition of sodium carbonate as alkalinizing agent precipitates the magnesium in the form of a species that remained dispersed in the bulk solution, favoring the contact angle of Cu-activated sphalerite and, consequently, its hydrophobicity. It is concluded that the use of sodium carbonate as alkalinizing agent favors the precipitation of magnesium as hydromagnesite (Mg5(OH)2(CO3)4∙4H2O) instead of hydroxide allowing the recovery of sphalerite.

Electron-Optical In Situ Imaging for the Assessment of Accuracy in Electron Beam Powder Bed Fusion

The current study evaluates the capabilities of electron-optical (ELO) in situ imaging with respect to monitoring and prediction of manufacturing precision in electron beam powder bed fusion. Post-process X-ray computed tomography of two different as-built parts is used to quantitatively evaluate the accuracy and limitations of ELO imaging. Additionally, a thermodynamic simulation is performed to improve the understanding of ELO data and to assess the feasibility of predicting dimensional accuracy numerically. It is demonstrated that ELO imaging captures the molten layers accurately (deviations <100 μm) and indicates the creation of surface roughness. However, some geometrical features of the as-built parts exhibit local inaccuracies associated with thermal stress-induced deformation (deviations up to 500 μm) which cannot be captured by ELO imaging. It is shown that the comparison between in situ and post-process data enables a quantification of these effects which might provide the possibility for developing effective countermeasures in the future.

Energy and Exergy Analyses of Fresh Water and Air Conditioning Production

Objective: For a combined generation of fresh water and air conditioning, the humidification-dehumidification and vapor compression refrigeration (HDH-VCR) cycle is the best option as it works at ambient pressure without handling any chemicals. Methods: The HDH cycle works on the principle of an artificially created water cycle. Air can be humidified either with heating and humidification or with the cooling and humidification process. The heating and humidification are well analyzed and the results are reported in the open literature. This work is focused on cooling and humidification for freshwater generation and air conditioning. In the current thermodynamic simulation, the identified key process conditions are evaporator temperature and ambient air conditions (temperature and relative humidity. Results: The focused results are specific desalination, specific cooling, energy performance ratio (EPR), and exergy efficiency. Conclusion: The resulted EPR for cycle and plant are 1.34 and 0.62 respectively at the evaporator temperature of -2 °C.