Microstructures and compressive properties of AlxCoCrFeNi high entropy alloys prepared by arc melting and directional solidification

The AlxCoCrFeNi (molar radio, x=0.6 and 1.2) high entropy alloys (HEAs) were prepared by arc melting and directional solidification at the withdrawal rate of 150 μm/s. All microstructures were characterized by x-ray diffraction, optical microscopy and scanning electron microscopy with an energy-dispersive spectrometer. Strong similarities in phase constituent were observed between the as-cast samples and directionally solidified samples. The Al0.6CoCrFeNi HEA and Al1.2CoCrFeNi HEA fabricated by two different techniques respectively consisted of Cr-Fe-Co enriched FCC phase + Al-Ni enriched BCC phase and Al-Ni enriched B2 phase + Cr-Fe-Co enriched A2 phase. It was micromorphology found that directional solidification could not only make the microstructures arranged regularly but also coarsen the grains. This has been attributed to the preferred grain orientation and lower cooling rate during directional solidification process. Compression testing showed that the compressive ductility of directionally solidified samples decreased obviously. The ultimate compressive strength of Al0.6CoCrFeNi HEA increased from 1 675 MPa to 1 903 MPa, but the strength of Al1.2CoCrFeNi HEA decreased from 2 183 MPa to 1 463 MPa. The difference in strength has been suggested to be the result of micropores in the matrix.

Study on the Solidification Behavior of Inconel617 Electron Beam Cladding NiCoCrAlY: Numerical and Experimental Simulation

To better control the Inconel617 electron beam cladding solidification process, a three-dimensional temperature field model was built to simulate the temperature gradient, cooling rate, and solidification rate in the solidification process and take a deep dive into the solidification behavior, as well as the calculation of the solidification characteristic parameters at the edge of the molten pool and then predict the solidification tissue structure. The study shows that the largest temperature gradient occurred in the material thickness direction. The self-cooling effect of the material dominated the solidification of the alloy layer; the cooling rate depended on the high-temperature thermal conductivity of the material and the self-cooling effect of the matrix, and the maximum cooling rate in the bonding zone was 1380 °C/s. The steady-state solidification rate was equal to the moving speed of the heat source; the solidification characteristics of the solidification process at the edge of the molten pool increased with the distance from the surface: the cooling rate decreased from 1421.61 to 623 °C/s, the temperature gradient increased from 0.0723 × 106 to 0.417 × 106, and the solidification rate decreased from 0.01 to 0 m/s. The prediction was made that the small and thin equiaxed crystals are on the top, a thin and short dendritic transition structure in the middle, and relatively coarse dendrites at the bottom. Experiments confirmed that the solidification tissue structure is basically consistent with the simulation law.

Zn22Al4Ag ALLOY MICROWIRES CASTING TO RAPID SOLIDIFICATION PROCESS BY ROTATING DRUM

In this work, the Zn22Al4Ag alloy was synthesized by melting in a muffle furnace.The alloy obtained was characterized by Scanning Electron Microscopy Energy Dispersive Spectroscopy and was analyzed by the X-Ray Diffraction technique, where the crystallinity of the material was verified before and after being processed. Likewise, the Differential Scanning Calorimetry technique was used to obtain the temperatures where phase transformations occurin the alloy. These results were fed to the Termocalc®, software to numerically obtain the phase diagram of the alloy. Subsequently, a section of the ingot was taken to the rapid solidification process by rotating drum. The process variables were manipulated: jet stability, nozzle diameter, distance from the nozzle surface to the cooling medium, the delay time of the molten material in the crucible, speed of the rotating drum and jet angle, until obtaining a microwire with a diameter of ~ 160µm. Finally, it was determined that inadequate control of these parameters can result in powders, flakes or blockage of the crucible outlet. Potentially uses within the micro and nanoworld as an analogy to structural elements and electrical conductors, in addition to its current use as a coating anti-corrosive. Key Words: ZnAlAg alloy, Melt spinning process, Microwire, DSC analysis, Thermodynamic simulation

Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel

A new glass solidification process aims at radioactive iodine waste was explored in order to reduce the possible harm to environment. Samples with different iodine content in silver-coated silica gel were pretreated by hydration device at 300 °C and then sintered at relatively low temperatures (500, 550 and 600 °C). XRD results show that AgI is mainly chemically fixed in the glass network with some AgI particles being physically wrapped by the glass. Moreover, as the sintering temperature reached to 550 °C, B element crystallized. SEM-EDS results show that Ag and I elements are enriched, while the other elements are evenly distributed. AFM results showed that the sample surface becomes rougher as the iodine content increases in the silver coated silica gel. The FT-IR results show that the structure of the sintered sample is mainly composed of [BiO3], [BiO6] and [BO3]. This study provides a new sintering method by hydration device for the treatment of radioactive iodine waste.

Study of Crack Sensitivity of Peritectic Steels

By comprehensively considering both the high temperature mechanical properties and peritectic transformation during peritectic steel solidification, the strain εCth is proposed to evaluate the crack sensitivity of peritectic steels produced in the brittle temperature range in the present work. The zero ductility temperature (ZDT) and the zero strength temperature (ZST) of Fe–C–0.32Si–1.6Mn–0.01P–0.015S steel under nonequilibrium conditions by taking the effect of the peritectic transformation on the solute segregation into account were calculated by the CK microsegregation model (Clyne–Kurz model) and were compared with the measured data. The comparison results show that this model can well simulate the nonequilibrium solidification process of peritectic steel. Then, based on the calculation of the CK microsegregation model, the strain during the peritectic phase transformation in the brittle temperature range (ZDT < TB < LIT) was calculated under nonequilibrium conditions. The results show that the calculated strain is in good agreement with the actual statistical longitudinal crack data indicating that the strain can therefore be used to predict the crack sensitivity of peritectic steels effectively.

Application of thermal analysis in ferrous and nonferrous foundries

This paper is devoted to the memory of Professor Ljubomir Nedeljkovic (1933-2020), Head of the Department of Iron and Steel Metallurgy University of Belgrade, Serbia. Assessment of the melt quality is one of the most important casting process parameters, which allowed sound production of intricated cast parts. At the present time, various devices have been applied at foundry floors to control melt quality. Thermal analysis is one of them, widely used for melt quality control in ferrous and non-ferrous casting plants. During solidification, metal and alloys released latent heat, which magnitude is dependent on the type of phases that form during the solidification process. Plotting temperature versus time data during solidification provides useful information related to the actual solidification process. The applied technique is called thermal analysis, whereas the cooling curve is the name of such a plot. The main aim of this paper is to give a short overview of the present thermal analysis application in various foundries and to indicate the future potential use of this technique.

Resistance spot welding of additively manufactured maraging steels Part I: Nugget formation

Application of additively manufactured steels is unavoidably involved in the resistance spot welding with conventionally manufactured steels. However, the microstructural evolution of an additive manufactured steel at high temperatures is still unknown, especially for the rapid solidification process. This paper investigated the microstructural evolution of a selective laser melted maraging steel during the rapid solidification process via resistance spot welding. Asymmetrical fusion zone with boat shape was found in the spot weld due to the rougher surface and larger electrical resistance of maraging steel via selective laser melting process. The rapid expansion of fusion zone at end of welding process was caused by the carbide formation at the heat-affected zone of maraging steel via selective laser melting process. Besides, printing orientation affected the surface roughness of a selective laser melted maraging steel and subsequently significantly influence the early stage of formation of fusion zone of additively manufactured maraging steel. We expect that our findings will pave the way to the future application of additively manufactured steels in the industries.

Quantitative Characterization of a Belt-cast High-Manganese Steel Microstructure

The description of the solidification process in casting processes with varying product thickness is characterized based on solidification structures, segregations as well as the primary and secondary microstructure. In near-net-shape casting processes, it is particularly challenging to achieve microstructure homogeneity in the as-cast condition, since the degree of forming in production processes up to hot or cold strip is lower than in the production of slabs or thin slabs. The density of shrinkage porosity in belt-cast high-manganese steel (HMnS) will be determined quantitatively using polished microsections. Following the visualization of the primary cast structure, light microscopic images will be obtained using different tint etches. For the evaluation of secondary dendrite arm spacing (SDAS), internally developed software based on ImageJ and Matlab will be used.