Theoretical Comparison of Optothermal Absorption in Transmissive Metalenses Composed of Nanobricks and Nanoholes

Background: Optical components with high damage thresholds are very desirable in intense-light systems. Metalenses, being composed of phase-control nanostructures with peculiar properties, are one of the important component candidates in future optical systems. However, the optothermal mechanism in metalenses is still not investigated adequately. Methods: In this study, the optothermal absorption in transmissive metalenses made of silicon nanobricks and nanoholes is investigated comparatively to address this issue. Results: The geometrical dependencies of nanostructures’ transmittance, phase difference, and field distribution are calculated numerically via simulations. To demonstrate the optothermal mechanism in metalenses, the mean absorption efficiencies of the selected unit-cells, which would constitute metalenses, are analyzed. The results show that the electric field in the silicon zone would lead to an obvious thermal effect, and the enhancement of the localized electric field also results in the strong absorption of optical energy. Then, two typical metalenses are designed based on these nanobricks and nanoholes. The optothermal simulations show that the nanobrick-based metalens can handle a power density of 0.15 W/µm2, and the density of the nanohole-based design is 0.12 W/µm2. Conclusions: The study analyzes and compares the optothermal absorption in nanobricks and nanoholes, which shows that the electric-field distribution in absorbent materials and the localized-field enhancement are the two key effects that lead to optothermal absorption. This study provides an approach to improve the anti-damage potentials of transmissive metalenses for intense-light systems.

Biochemical Basis for the Time-of-Day Effect on Glufosinate Efficacy against Amaranthus palmeri

Glufosinate, a glutamine synthetase (GS) inhibitor, often provides variable weed control depending on environmental conditions such as light, temperature and humidity at the time of application. Midday applications normally provide improved efficacy compared to applications at dawn or dusk. We investigated the biochemical basis for the time-of-day effect on glufosinate efficacy in Amaranthus palmeri. GS1/GS2 gene expression and GS1/GS2 protein abundance were assessed in different parts (young leaves, old leaves, and roots) of plants incubated in the dark compared to those in the light. The turnover of GS total activity was also evaluated overtime following glufosinate treatment at midday compared to dusk application. The results suggest that GS in A. palmeri is less expressed and less abundant in the dark compared to in the light. Midday application of glufosinate under intense light conditions following application provide full control of A. palmeri plants. Consequently, these plants are unable to recover GS activity by de novo protein synthesis. Full activity of GS is required for complete inhibition by the irreversible inhibitor glufosinate. Therefore, glufosinate applications should always be performed in the middle of the day when sunlight is intense, to prevent weed escapes from the herbicide treatment.

Synthesis and Spectroscopic Characterization of Thienopyrazine-Based Fluorophores for Application in Luminescent Solar Concentrators (LSCs)

Organic fluorophores have found broad application as emitters in luminescent solar concentrators (LSCs) for silicon photovoltaics. In particular, the preparation of organic conjugated systems with intense light-harvesting ability, emissions in the deep-red and NIR regions, and large Stokes shift values represent a very challenging undertaking. Here, we report a simple and easy way to prepare three symmetrical donor–acceptor–donor (DAD) organic-emitting materials based on a thienopyrazine core. The central core in the three dyes was modified with the introduction of aromatic substituents, aiming to affect their optical properties. The fluorophores were characterized by spectroscopic studies. In all cases, visible-NIR emissions with large Stokes shifts were found, highlighting these molecules as promising materials for the application in LSCs.

Observation of light induced dynamical band structure via multi-band high harmonic spectroscopy

Intense light-matter interactions have revolutionized our ability to probe and manipulate quantum systems at sub-femtosecond time scales, opening routes to all-optical control of electronic currents in solids at petahertz rates, the time-scale of a single optical cycle. Such control typically requires electric field amplitudes ~V/A, when the voltage drop across a lattice site becomes comparable to the characteristic band gap energies. In this regime, intense light-matter interaction induces significant modifications of electronic and optical properties and is certain to dramatically modify the band structure of the light-dressed crystal. Yet, identifying and characterizing such modifications remains an outstanding problem. As the oscillating electric field changes from V/A to zero within a quarter-cycle of the driving field, does the band-structure follow, and how can it be defined? Here we address this fundamental question, proposing all-optical spectroscopy of strongly driven crystals, and probe laser-induced closing of the band-gap between adjacent conduction bands. Our work reveals the link between extreme nonlinear light matter interactions in strongly driven crystals to the sub-cycle modifications in their effective band structure.

Regeneration Dynamics on Treefall Mounds and Pits for 10 Years after a Windfall in a Natural Mixed Forest

The treefall mounds and pits resulting from uprooting caused by strong winds is an indispensable microtopography for the regeneration of many tree species through improved light conditions and mineral soil exposure. These microtopographies are expected to become more important because global warming is predicted to increase windstorm frequency. This study aimed to clarify the characteristics of mounds and pits that contribute to the early establishment of major tree species in a natural mixed forest of northern Japan. The 39 tip-up mounds caused simultaneously by a strong typhoon in September 2004 were selected. In 2006, light intensity and soil moisture contents were measured in each mound and pit. Seedlings of all tree species were counted, and in 2014, the height of saplings was measured. The initial seedling density, regardless of tree species, was significantly higher in the pits than on the mound, but the density at the 10-th growing season decreased significantly in the pits and was comparable between the two locations. Intense light conditions favor regeneration of Betula sp. (Betula platyphylla and B. ermanii). In contrast, for Abies sachalinensis and Picea glehnii, the light intensity had a negative effect, so it was concluded that regeneration of conifers would be limited under the condition where strong winds form large gaps.

Resonant X-ray emission spectroscopy from broadband stochastic pulses at an X-ray free electron laser

Hard X-ray spectroscopy is an element specific probe of electronic state, but signals are weak and require intense light to study low concentration samples. Free electron laser facilities offer the highest intensity X-rays of any available light source. The light produced at such facilities is stochastic, with spikey, broadband spectra that change drastically from shot to shot. Here, using aqueous ferrocyanide, we show that the resonant X-ray emission (RXES) spectrum can be inferred by correlating for each shot the fluorescence intensity from the sample with spectra of the fluctuating, self-amplified spontaneous emission (SASE) source. We obtain resolved narrow and chemically rich information in core-to-valence transitions of the pre-edge region at the Fe K-edge. Our approach avoids monochromatization, provides higher photon flux to the sample, and allows non-resonant signals like elastic scattering to be simultaneously recorded. The spectra obtained match well with spectra measured using a monochromator. We also show that inaccurate measurements of the stochastic light spectra reduce the measurement efficiency of our approach.

Enhancement of astaxanthin accumulation using black light in Coelastrum and Monoraphidium isolated from Malaysia

Microalgae are important microorganisms which produce potentially valuable compounds. Astaxanthin, a group of xanthophyll carotenoids, is one of the most powerful antioxidants mainly found in microalgae, yeasts, and crustaceans. Environmental stresses such as intense light, drought, high salinity, nutrient depletion, and high temperature can induce the accumulation of astaxanthin. Thus, this research aims to investigate the effect of black light, also known as long-wave ultraviolet radiation or UV-A, as a stressor on the accumulation of astaxanthin as well as to screen the antioxidant property in two tropical green algal strains isolated from Malaysia, Coelastrum sp. and Monoraphidium sp. SP03. Monoraphidium sp. SP03 showed a higher growth rate (0.66 day−1) compared to that of Coelastrum sp. (0.22 day−1). Coelastrum sp. showed significantly higher accumulation of astaxanthin in black light (0.999 g mL culture−1) compared to that in control condition (0.185 g mL−1). Similarly, Monoraphidium sp. SP03 showed higher astaxanthin content in black light (0.476 g mL culture−1) compared to that in control condition (0.363 g mL culture−1). Coelastrum sp. showed higher scavenging activity (30.19%) when cultured in black light condition, indicating a correlation between the antioxidant activity and accumulation of astaxanthin. In this study, black light was shown to possess great potential to enhance the production of astaxanthin in microalgae.

Reflective Meta-Films with Anti-Damage Property via Field Distribution Manipulation

The reflective optical multi-films with high damage thresholds are widely used in intense-light systems. Metasurfaces, which can manipulate light peculiarly, give a new approach to achieve highly reflective films by a single-layer configuration. In this study, reflective metasurfaces, composed of silicon nanoholes, are numerically investigated to achieve high damage thresholds. These nanoholes can confine the strongest electric field into the air zone, and, subsequently, the in-air electric field does not interact directly with silicon, attenuating the optothermal effect that causes damage. Firstly, the geometrical dependencies of silicon nanoholes’ reflectance and field distribution are investigated. Then, the excitation states of electric/magnetic dipoles in nanostructures are analyzed to explain the electromagnetic mechanism. Furthermore, the reflection dependences of the nanostructures on wavelength and incident angle are investigated. Finally, for a typical reflective meta-film, some optothermal simulations are conducted, in which a maximum laser density of 0.27 W/µm2 can be handled. The study provides an approach to improve the laser damage threshold of reflective nanofilms, which can be exploited in many intense-light applications.