Lead Corrosion and Corrosivity Classification in Archives, Museums, and Churches

Sixteen localities were involved in a broad study, resulting in the classification of the indoor corrosivity of metals considered in the ISO 11844 standard, especially lead. Recently, lead has been added to the standard as a metal specifically sensitive to volatile organic compounds such as acetic acid. Data on one-year exposure in museum depositories and exhibition spaces, archives, libraries, and churches show that the currently valid lead corrosivity categories are not correctly defined. The obtained data allowed for the proposal of new realistic ranges of indoor corrosivity categories for lead. The exposure program was also used to validate techniques for determining the corrosion degradation of metal coupons. Mass increase and mass loss techniques were supplemented with the galvanostatic reduction technique and the measurement of color changes. The study identified the limitations of the mass gain method. Not only is the galvanostatic reduction technique applicable for silver and copper coupons, but the build-up of reducible lead corrosion products depends on air corrosivity. CIELab color-change measurement has proven to be a simple and easy-to-apply method for monitoring the corrosivity of indoor atmospheres with regard to lead. A more reliable response is provided by the determination of color change after 3 months of exposure rather than after one year.

Atmospheric Pressure Change Measurement: An Observational Study

Introduction: The aim of the study was to show an atmospheric pressure change by indirect measurement in hermetically closed vessels during four years of follow-up.Methods: Study design: an observational study. In hermetically sealed elastic bottles with different liquids were measured differences in liquid and air volumes from baseline to final follow-up period. The physical law of flotation was used to measure liquid and air volume above liquid in bottles. To measure liquid and air (above liquid) volumes in each bottle was used the physical law of buoyancy. The follow-up period was four years.Results: The volumes of liquid and air in all bottles were decreased after the follow-up period to 14.38±2.40 and 36.25±3.37 ml, respectively. Air volume in comparison to liquid volume decreased more than two times significantly (P=0.0007) after the follow-up period.Conclusions: Thus, atmospheric pressure increased during the last 4-year follow-up period. Further investigations are needed.

Effect of Time of Day on the Magnitude of Stature Change Response Variability in Participants with Chronic Low Back Pain on Consecutive 2 Days

Measurements of stature change have been used to compare spinal loading in the sitting posture. However, it is difficult to interpret whether the stature change response recorded is truly due to an intervention or to the natural fluctuation of stature change response between the days. The aim of this study was to investigate the effect of time of day (morning and afternoon) on the variability of stature change in participants with chronic low back pain (CLBP) on 2 consecutive days. Forty-four participants with CLBP attended 2 sessions (morning and afternoon) of stature change testing on 4 separate days. A stature change response of more than 0.985 mm in the morning and 1.149 mm in the afternoon on 2 consecutive days indicates that an intervention itself has influenced stature change measurement in CLBP participants. The magnitude of stature change response on different days and times of day established specific levels of natural variation meaning changes above these levels can be attributed to intervention effects in participants with CLBP. HIGHLIGHTS The findings suggest that it is important to control the time at which stature change investigations are conducted Seated stadiometry measurement, changes above 0.985 mm (morning) and 1.149 mm (afternoon) can be attributed to intervention effects between consecutive 2 days The results of the current study presented no significant difference in magnitude of stature change response in the morning versus the afternoon in chronic low back pain participants GRAPHICAL ABSTRACT

Desorption Studies for Methylene Blue Dye Removal by Kaolinite

In wastewater treatment, the reusability of an adsorbent strongly relies on the feasibility of contaminant desorption from the spent adsorbent. This research aims to investigate the Methylene Blue (MB) release from the spent kaolinite clay mineral against a variety of desorbing eluent in an aqueous solution. Malaysia’s kaolinite was characterised using Scanning Electron Microscopy (SEM), surface area analysis, and Fourier Transform Infrared (FTIR) Spectroscopy. The MB desorption was performed using eluents of distilled water, solutions of HCl, NaOH, and NaCl (0.01 M and 0.1 M), and ethanol: water mixtures (30:70, 50:50, and 70:30 v/v ratios). It was found that the MB desorption only occurs in 0.1 M NaOH (pH 12.7). A 4.2% MB desorption was recorded in 1 hour and was increased to 19.5% within 24 hours desorption time. The pH change measurement also reveals the favorability for highly alkaline conditions for MB desorption. The overall finding indicates that the MB retention towards kaolinite is strong, and its adsorption occurs via electrostatic and hydrophobic interaction, as suggested by the FTIR analysis. Kaolinite is a good scavenger for removing the MB dye from contaminated water but requires a strong eluent in the desorption process for its future reusability process.

Oddziaływanie społeczne przedsiębiorstw społecznych w teorii i praktyce

The publication is devoted to issues related to the development of tools for measuring social impact generated by social enterprises. A valuable aspect of the monograph is the inclusion of case studies of selected tools (such as social return on investment, local multiplier, balanced scorecard) in partnership with social enterprises. The authors pay special attention to solutions enabling the operationalization of social change measurement, taking into account not only financial but, above all, non-financial aspects. They believe that the measurement of impact should take into account not only the economic perspective, but also the public and social one, where values other than material profit also count. The tools should indicate the responsibility of entities towards various types of stakeholders and serve to increase the quality of social services by providing valuable information to individual organizations.

Heat Generation in NMC622 Coin Cells during Electrochemical Cycling: Separation of Reversible and Irreversible Heat Effects

The thermal behavior of a commercial lithium-ion cell with the cathode material LiNi0.6Mn0.2Co0.2O2 (NMC622) was investigated during the cycling process using a Tian-Calvet calorimeter (C80, SETARAM Instrumentation, France). Various current flows of 42.5, 85, and 170 mA corresponding to charging rates of 0.5, 1, and 2 C, respectively, were applied in the measurements. The corresponding heat flow rates were measured by the C80 calorimeter at 30 °C. The reversible heat effect due to the reversible electrochemical reaction was quantified by the entropy change measurement. The irreversible heat effect due to internal resistances was determined by the electrochemical impedance spectroscopy (EIS) and the galvanostatic intermittent titration technique (GITT). The results were compared with the direct measurement of the heat effect by calorimetry during electrochemical cycling.