Transient Response of Polymer Electrolyte Membrane Fuel Cell to Variations in Operating Parameters

Due to rapid change in loads during automotive applications, study of dynamic behavior of proton exchange membrane (PEM) fuel cells is of paramount importance for their successful deployment in mobile applications. Toward understanding the effects of changes in operating parameters on the transient behavior, this paper presents numerical simulations for a single channel PEM fuel cell undergoing cyclic changes in operating parameters. The objective is to elucidate the complex interaction between power response and complex species (water, hydrogen and oxygen) transport dynamics for applied cyclic changes. This study focuses on studying the transient response of fuel cell for specified changes in operating parameters — voltage, pressure and stoichiometry at the cathode and the anode. Numerical studies are carried out on single-channel PEMFC’s to illustrate the response of power as the operating parameters are subjected to specified changes. The operating parameters are further optimized using a one dimensional physics based model with an objective to match the power requirements of a drive cycle over a defined period of time.

Water Management in PEMFC With Ultra-Thin Catalyst-Layers

A two-dimensional non-isothermal multi-physics proton-exchange-membrane fuel-cell (PEMFC) modeling has been undertaken to investigate the interplay between the platinum (Pt) loading, water-capacity, water transport and cell performance at low operating temperatures (< 40 °C). Two ultra-thin catalyst layers (CLs), traditional Pt/C with extremely low Pt loading and nano-structured thin-film (NSTF), have been the main focus in the present model. Modeling data are compared with experimental polarization curves for both NSTF and traditional Pt/C CLs. Using the model, the interplay between the inherent CL water-capacity versus its removal rate through either the anode or cathode side of the PEMFC is explored. The controlling parameters for the water removal and accumulation (e.g., thickness of catalyst layer, existence of microporous layer, etc.) are also analyzed and the tradeoff between these parameters elucidated with a path towards efficient water management for ultra-thin CLs.

A Parameter Identification Approach of a PEM Fuel Cell Stack Using Particle Swarm Optimization

The fear of fossil fuels depletion as well as the constantly increasing pollution rates motivated most of today’s engineers and researchers towards focusing on renewable energies and their applications. Fuel Cells are one of the green technologies that are being explored extensively around the world. The work of this paper was done on the 3kW ElectraGen™ fuel cell system under study for domestic use in the United Arab Emirates (UAE). Several experiments were conducted at different operating points and relatively high ambient temperatures. The experimental I/V characteristics of the system are matched by identifying 13 different modeling parameters using basic fitting. The obtained model is then further optimized using Particle Swarm Optimization (PSO). The resulting model is validated experimentally and was found to highly resemble the system’s I/V characteristics yielding less than 1.5 V H∞ norm of the error.

Comparison of Solid Oxide Fuel Cell Stack Performance Using Detailed and Simplified Models

Two computational fluid dynamics models have been developed to predict the performance of a solid oxide fuel cell stack, a detailed and a simplified model. In the detailed model, the three dimensional momentum, heat, and species transport equations are coupled with electrochemistry. In the simplified model, the diffusion terms in the transport equations are selectively replaced by rate terms within the core region of the stack. This allows much coarser meshes to be employed at a fraction of the computational cost. Following the mathematical description of the problem, results for a single cell and multi-cell stack are presented. Comparisons of local current density, temperature, and cell voltage indicate that good agreement is obtained between the detailed and simplified models, confirming the validity of the latter as a practical option in stack design.

Effect of PTFE on Thermal Conductivity of Gas Diffusion Layers of PEM Fuel Cells

Through-plane thermal conductivity of 14 SIGRACET gas diffusion layers (GDLs), including series 24 & 34, as well as 25 & 35, are measured under different compressive pressures, ranging from 2 to 14 bar, at the temperature of around 60 °C. The effect of compression, PTFE loadings, and micro porous layer (MPL) on thermal conductivity of the GDLs and their contact resistance with an iron clamping surface is experimentally investigated. The contact resistance of MPL coated on GDL with the substrate of that GDL is measured for the first time in this paper. A new robust mechanistic model is presented for predicting the through-plane thermal conductivity of GDLs treated with PTFE and is successfully verified with the present experimental data. The model can predict the experimentally-observed reduction in thermal conductivity as a result of PTFE treatment and provides detailed insights on performance modeling of PEMFCs.

Effect of Porosity and Thermal Conductivity of a Porous Transport Layer on Saturation and Thermal Transport in a Low-Temperature Fuel Cell

Water transport in the Porous Transport Layer (PTL) plays an important role in the efficient operation of polymer electrolyte membrane fuel cells (PEMFC). Excessive water content as well as dry operating conditions are unfavorable for efficient and reliable operation of the fuel cell. The effect of thermal conductivity and porosity on water management are investigated by simulating two-phase flow in the PTL of the fuel cell using a network model. In the model, the PTL consists of a pore-phase and a solid-phase. Different models of the PTLs are generated using independent Weibull distributions for the pore-phase and the solid-phase. The specific arrangement of the pores and solid elements is varied to obtain different PTL realizations for the same Weibull parameters. The properties of PTL are varied by changing the porosity and thermal conductivity. The parameters affecting operating conditions include the temperature, relative humidity in the flow channel and voltage and current density. A parametric study of different solid-phase distributions of the PTL and its effect on thermal, vapor and liquid transport in the PTL under different operating conditions are discussed.

Effect of Gravity on Droplet Growth and Detachment Inside a Simulated PEM Fuel Cell Air Flow Channel With Hydrophobic Walls

Water management still remains a challenge for proton exchange membrane fuel cells. Byproduct water formed in the cathode side of the membrane is wicked to the air supply channel through the gas diffusion layer. Water emerges into the air supply channel as droplets, which are then removed by the air stream. When the rate of water production is higher than the rate of water removal, droplets start to accumulate and coalesce with each other forming slugs consequently clogging the channels and causing poor fuel cell performance. It has been shown in previous experiments that rendering the channels hydrophobic or super-hydrophobic cause water droplets to be removed faster, not allowing time to coalesce, and therefore making channels less prone to flooding. In this numerical study we analyze water droplet growth and detachment from a simulated hydrophobic air supply channel inside a proton exchange membrane (PEM) fuel cell. In these numerical simulations the Navier-Stokes equations are solved using the SIMPLER method coupled with the level set technique in order to track the liquid-vapor interface. The effect of the gravity field acting in the −y, −x, and +x directions was examined for an array of water flow rates and air flow rates. Detachment times and diameters were computed. The results showed no significant effect of the gravity field acting in the three different directions as expected since the Bond and Capillary numbers are relatively small. The maximum variations in detachment time and diameter were found to be 8.8 and 4.2 percent, respectively, between the horizontal channel and the vertical channel with gravity acting in the negative x direction, against the air flow. Droplet detachment was more significantly affected by the air and water flow rates.

In-Plane Microstructure of Gas Diffusion Layers With Different Properties for PEFC

Gas diffusion layer (GDL) is undoubtedly one of the most complicated components used in a polymer electrolyte fuel cell (PEFC) in terms of liquid and gas transport phenomena. An appropriate fuel cell design seeks a fundamental study of this tortuous porous component. Currently, porosity and gas permeability have been known as some of the key parameters affecting liquid and gas transport through GDL. Although these are dominant parameters defining mass transport through porous layers, there are still many other factors affecting transport phenomena as well as overall cell performance. In this work, microstructural properties of Toray carbon papers with different thicknesses and for polytetrafluoroethylene (PTFE) treated and untreated cases have been studied based on scanning electron microscopy (SEM) image analysis. Water droplet contact angle as a dominant macroscale property as well as mean pore diameter, pore diameter distribution, and pore roundness distribution as important microscale properties have been studied. It was observed that the mean pore diameter of Toray carbon paper does not change with its thickness and PTFE content. Mean pore diameter for Toray carbon papers was calculated to be around 26μm regardless of their thicknesses and PTFE content. It was also observed that droplet contact angle on GDL surface does not vary with GDL thickness. The average contact angle for 10 wt.% PTFE treated GDLs of different thicknesses was measured about 150°. Finally, the heterogeneous in-plane PTFE distribution on the GDL surface was observed to have no effect on mean pore diameter of GDLs.

Using Shewanella Oneidensis MR1 as a Biocatalyst in a Microscale Microbial Fuel Cell

Microbial fuel cell (MFC) technology is a promising area in the field of renewable energy because of their capability to use the energy contained in wastewater, which has been previously an untapped source of power. Microscale MFCs are desirable for their small footprints, relatively high power density, fast start-up, and environmentally-friendly process. Microbial fuel cells employ microorganisms as the biocatalysts instead of metal catalysts, which are widely applied in conventional fuel cells. MFCs are capable of generating electricity as long as nutrition is provided. Miniature MFCs have faster power generation recovery than macroscale MFCs. Additionally, since power generation density is affected by the surface-to-volume ratio, miniature MFCs can facilitate higher power density. We have designed and fabricated a microscale microbial fuel cell with a volume of 4 μL in a polydimethylsiloxane (PDMS) chamber. The anode and cathode chambers were separated by a proton exchange membrane. Carbon cloth was used for both the anode and the cathode. Shewanella Oneidensis MR-1 was chosen to be the electrogenic bacteria and was inoculated into the anode chamber. We employed Ferricyanide as the catholyte and introduced it into the cathode chamber with a constant flow rate of approximately 50 μL/hr. We used trypticase soy broth as the bacterial nutrition and added it into the anode chamber approximately every 15 hours once current dropped to base current. Using our miniature MFC, we were able to generate a maximum current of 4.62 μA.

Design and Balance-of-Plant of a Demonstration Plant With a Solid Oxide Fuel Cell Fed by Biogas From Waste-Water and Exhaust Carbon Recycling for Algae Growth

The design and balance-of-plant of an integrated anaerobic digestion (AD) biogas solid oxide fuel cell (SOFC) demonstration plant is presented. A notable feature of the plant is the CO2 capture from the SOFC anode exhaust via an oxy-combustion reactor. The captured CO2 is fed to a photobioreactor installation downstream of the SOFC where C is fixed in an algae bio-fuel. The main plant sections are described in detail including the gas cleaning unit, fuel processing, SOFC ‘hot-box’, oxy-combustor, CO2/H2O condensation unit and finally algae bioreactor. The demonstration plant is fed with biogas from AD of the by-product sludge of the greatest waste-water treatment plant in Italy, serving over 2 million population equivalents in the Torino metropolitan area. In this work, the main BoP components and engineering issues concerning the design of the SOFC plant are detailed. The as-produced biogas is firstly treated to remove moisture and then filtered to remove sulfur, halogens and siloxanes. Dry clean biogas (roughly 60–65% CH4, 35–40% CO2) is sent to a steam-reformer. The reformate gas is thus used to feed a 2 kWe SOFC module (operated at ∼ 800 °C). The cathode off-gas is kept separated from the anode and is used to pre-heat inlet fresh air; the anode outlet stream is sent first to an oxy-combustor to yield an almost pure H2O-CO2 mixture that is eventually cooled down to 300–400 °C. Steam is condensed and separated in a dedicated condenser unit. The resulting pure CO2 is thus pressurized (8 bar) and available for sequestration or other uses. Due to the limited size of the demo plant, the choice was to feed it to bioreactors with algae, where the latter are grown with sunlight and CO2 indeed. A tubular photo-bioreactor has been chosen with a productivity of 20 g/day/m2 of dry algae. The outlet stream will be an algae purge that, due to its low mass flow, could be re-sent to the biogas digesters. A system analysis of a scaled-up version of the biogas fed SOFC power plant, with heat integration included, is also carried out with a calculated overall electrical efficiency exceeding 55% (LHV basis).