Properties of nickel-based superalloys of equiaxial crystallization

Purpose. The aim of the work is to obtain predictive regression models, with the help of which, it is possible to adequately calculate the mechanical properties of nickel-based superalloys of equiaxial crystallization, without carrying out preliminary experiments. Research methods. To find regularities and calculate the latest CALPHAD method was chosen, and modeling of thermodynamic processes of phase crystallization was performed. Results. As a result of experimental data processing, the ratio of alloying elements Kg¢ was proposed for the first time, which can be used to assess the mechanical properties, taking into account the complex effect of the main alloy components. The regularities of the influence of the composition on the properties of heat-resistant nickel alloys of equiaxial crystallization are established. The analysis of the received dependences in comparison with practical results is carried out. The relations well correlated with heat resistance, mismatch and strength of alloys are obtained. Scientific novelty. It is shown that for multicomponent nickel systems it is possible with a high probability to predict a mismatch, which significantly affects the strength characteristics of alloys of this class. The regularities of the influence of the chemical composition on the structure and properties of alloys are established. A promising and effective direction in solving the problem of predicting the main characteristics of heat-resistant materials based on nickel is shown Practical value. On the basis of an integrated approach for multicomponent heat-resistant nickel-based alloys, new regression models have been obtained that make it possible to adequately predict the properties of the chemical composition of the alloy, which made it possible to solve the problem of computational prediction of properties from the chemical composition of the alloy. This allows not only to design new nickel-based alloys, but also to optimize the composition of existing brands.

The problem of formation and ergonomics of ecologically compact electric transport

The problem of formation and ergonomics of ecologically compact electric transport

Model of the impurities redistribution in the surface layer of an alloy under the action of pulsed laser radiation

Model of the impurities redistribution in the surface layer of an alloy under the action of pulsed laser radiation

Professional direction of physics teaching of future engineers: practical aspect

Professional direction of physics teaching of future engineers: practical aspect

Obtaining tube blanks from copper-nickel alloy МНЖ 5-1 when using a tool made of die steel adjustable austenitic transformation during operation

Purpose. Production of die tool from steel with regulation of austenitic transformation during operation to increase the level of service life during hot deformation of copper-nickel alloy. Research methods. Metallographic, high-temperature X-ray phase and dilatometric analyzes of research steel. Results. The mode of heat treatment (incomplete annealing) of steel 4Х3Н5М3Ф at a temperature of 750±20 °С, obtained by electroslag remelting, allowed to obtain a perlite-sorbitol structure at a hardness of33–34 HRC and allowed better machining by cutting the workpiece alloy. The proposed mode of final heat treatment (hardening 1030±10 °C and tempering 600±5 °C) of the investigated steel, makes it possible to heat the matrix during operation to a temperature of 600 °C. Scientific novelty. The thermal stability of the tool for hot deformation can be significantly increased when using steel with adjustable austenitic transformation during operation. Such steel in the initial state has a ferrite base, and when heated to operating temperatures occurs from α-Fe to γ-Fe conversion and, subsequently, the austenitic structure is preserved throughout the period of high-temperature operation of the stamping tool. It is confirmed that the stamping tool made of steel 4Kh3N5М3F when pressing a copper-nickel alloy works in the temperature range corresponding to the austenitization process. Practical value. Abbreviated technological operation, namely thermo-deformation processing (forging) of ingots obtained by electroslag remelting. Experimental-industrial tests of the die tool of steel 4Х3Н5М3Ф in the manufacture of tube blanks of Ø 67±0,1 mm from a copper-nickel alloy of the МНЖ 5-1 brand are carried out. As a result of research “Artemovsk plant for processing of non-ferrous metals and alloys” (Bakhmut, Donetsk region, Ukraine) at an operating temperature of 900–950 ° C, matrices made of steel 4Х3Н5М3Ф (without deformation-forging) showed stability in three times higher than the matrices from steel 3Х3М3Ф made at the enterprise.

Unidirectional crystallization and 3D structure of ternary four-component eutectic of B4C-NbB2-SiC system

Purpose. To investigate the laws of crystallization and formation of 3D morphology of ternary eutectics in system B4C-NbB2-SiC. Research methods. SEM (SE, BSE), РСМА (EDS, WDS), XRD. Results. The micro- and macro-morphology of eutectic colonies in alloys of the system NbB2-SiC-В4С formed during directional crystallization have been investigated. The obtained patterns are embodied in a 3D structural model of (B4C+NbB2+SiC) eutectic cell and from these result, a microscopic kinetics of crystallization of this cell was proposed. The continuity of eutectic phase dendrites from nucleation to the end of growth and inadequacy of ideas about eutectic as a mechanical mixture of small crystals of eutectic phases were shown. Scientific novelty. For the first time a 3D model of a three-phase 4-component eutectic cell of eutectic colony was built. For the first time the possibility of combined microscopic crystallization kinetics of a three-phase eutectics was revealed, including both paired cooperative microscopic kinetics of (SіC+ NbB2) growth and the kinetics of autonomous growth of the third eutectic phase B4C. Practical value. Revealing the pattern of micro and macrostructure formation of a three-phase eutectics, which was formed in the course of directional crystallization, opens up technological prospects for purposeful control of the structure and properties of eutectic alloy due to the change of micro and macro morphological constituents, including the method of modification.

The influence of aluminum on the formation of the hardening phase in magnesium alloys

Purpose. Study of the effect of alloying with aluminum on structure formation, mechanical properties and heat resistance of magnesium alloys Research methods. Methods of metallographic and micro X-ray spectral analysis. Determination of mechanical properties and heat resistance. Results. The regularities of the influence of alloying with aluminum on the formation of the hardening phase in magnesium alloys have been investigated. It is shown that an increase in the concentration of aluminum in magnesium alloy promotes refinement of the macro- and microstructure of the metal (reduces the grain size and the distance between the second-order dendritic axes) and also increases the amount of intermetallic phase. The positive effect of aluminum additives on the mechanical properties and heat resistance of cast metal has been established. The optimal level of alloying with aluminum (about 7,7 %) hes been determined, which ensures a sufficient level of mechanical properties and heat resistence. Scientific novelty. Based on the regression analysis of the experimental data, empirical equations were obtained that describe the dependences of the size of macro- and micrograins on the concentration of aluminum in magnesium alloys. It is shown that the optimal aluminum content in the magnesium alloy in the amount of ~ 7,7 % provides the best combination of mechanical properties (a sufficiently high strength and the highest plasticity) and heat resistance Practical value. It has been established that alloying magnesium alloys with aluminum is promising for improving the structure and increasing the mechanical properties and heat resistance of cast metal. This effect makes it possible to significantly expand the field of application of magnesium alloys in mechanical engineering and improve the performance of various equipment.

Stress-deformed state of the shell with a small initial deflection under the action of the end load

Purpose of work. Construction of method for calculating the stress-strain state of cylindrical shell with small initial deflection, to which an end load is applied, using the method of characteristics. Comparison of the calculation results of the obtained model with the works of other authors in this area. Research methods. For the calculation, the equations of motion of the Timoshenko type shell were used, taking into account both the shear deformation and inertia of rotation, and some nonlinear terms, to which the method of characteristics was applied. To obtain the equations of shell motion, the Hamilton-Ostrogradsky variational principle was used. Results method is proposed for calculating the stress-strain state of a cylindrical shell with a small initial deflection using characteristics. Comparative analysis of the calculation results with research in this area by other authors, which showed the effectiveness of the proposed method. Scientific novelty. The equations of the classical theory of shells, based on the Kirchhoff-Love hypotheses, which do not take into account the shear deformation and inertia of rotation, as well as linear equations of the Timoshenko type, have become widespread. In this work, a model of the stress-strain state of an axisymmetric shell with small initial deflections is constructed, taking into account both shear deformation and rotational inertia, and some nonlinear terms. Practical value. The proposed method can be used to calculate the stress-strain state of structures in which thin shells are present as elements, taking into account small initial deflection. This method makes it possible to study the influence of the characteristics of the initial deflection on the stress-strain state of the entire structure.

Features of the process of hot extrusion of blanks of the rotor blades of a GTE compressor

Purpose. Improving the quality of manufacturing of blanks for compressor rotor blades by hot extrusion. Research methods and equipment. The research was carried out using a crank press with a force of 1000 kN, in split dies in accordance with a serial technological process. The dies were heated up to 150 ... 200 °С, to improve the work when extruding the blanks of the rotor blades made from the titanium alloy ВT8. The thickness of the copper coating was measured with an ИTMП-3 magnetic induction device with an error of ± 2 μm. X-ray spectral microanalysis was performed on an ISM-6360ALA scanning microscope. The billets were heated in an MП-2В furnace. Results. It has been established that the quality of blade blanks made of ВT8 titanium alloy obtained by hot extrusion is influenced by the state of the copper coating, which is preliminarily applied to the surface of the original blank. When the initial blanks are heated, copper is oxidized and in the temperature range of 250…700 °С the oxidation rate proceeds according to a linear pattern, and after 700…750 °С – according to a parabolic pattern. Oxidation of the copper coating occurs unevenly not only within one workpiece, but also within the batch, which leads to a decrease in durability and deterioration of the surface quality of the blade workpieces obtained by hot extrusion. Research carried out by X-ray spectral microanalysis of the copper coating revealed the presence of aluminum oxides of varying degrees of dispersion. The source of this material in the copper coating is caricature of corundum used in blowing into the surface of the billet, which is the reason for the appearance of scoring on the blade blank. It was also found that longitudinal marks on the blade are a consequence of the appearance of a matrix of tubercles (sagging) on the working surface of the die, caused by the adhesion of the deformable material of the blade to the base metal of the tool. Scientific novelty. The regularity of the influence of the heating temperature of the initial blank of the blade on the oxidation rate of the copper coating has been established. The mechanism of the influence of the oxidation of the copper coating and the adhesion of contacting materials during hot extrusion on the surface condition of the resulting blanks is disclosed. Practical value. The results obtained make it possible to improve the quality of the manufactured blanks of the compressor rotor blades by hot extrusion.

Method of arc activation of the base at increasing the distance plasma spraying

Purpose. To increase the efficiency of the plasma coating by developing a method of ion-arc activation of the base using an activating electrode, which leads to an increase in the adhesion strength of the coating due to the sputtering of surface oxides of the base. Research methods. Experimental and computational, mechanical tests, optical microscopy. The development of the method of ion-arc activation of the part base with an increase in the distance of coating deposition consists in application of an activating electrode located at the surface of the base to create an additional activating arc. The influence of the activating arc on bases for creating an additional activating arc. The influence of the activating arc on the adhesion strength of the coating is determined. The estimation of the current density of the activating arc for the sputtering of surface base oxides is carried out. Results. A method of arc activation of the base surface with an increase in the coating distance is found. It is shown that application of an activating arc of reverse polarity that burns between the additional electrode and the base leads to ion bombardment of the surface by sputtering surface oxides and the creation of microcraters on the base surface. As a result, the bond strength is doubled compared to the bond strength obtained without the use of ion-arc activation of the base. The calculations of the rate of cathodic sputtering of the surface oxides of the base are carried out and the minimum activation current density of the base is determined, which leads to the complete sputtering of a layer of oxides of a given thickness. Scientific novelty. It has been determined that, despite the rapid oxidation of the base under atmospheric conditions, application of the method of ion-arc cleaning of the surface during coating leads to a significant increase in the adhesion strength of the coating to the base. Practical value. The obtained results of increasing the adhesion strength rise the efficiency, the guaranteed service life of the plasma coating on the parts of machines and mechanisms