Reduction of Gd6UO12 for the Synthesis of Gd6UO11
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ABSTRACTIn the present work, we focus on δ-Gd6UO12 phase and its stability under reducing conditions. This later point is interesting regarding reducing environment that could exist in some nuclear storage sites and that could possibly degrade δ–compounds. A polycrystalline δ-Gd6UO12 sample was prepared by sintering cubic-Gd2O3 and UO2 mixed powders under an air atmosphere. The resulting pellets were then characterized and reduced by heat treatment under an Ar with H2 5% atmosphere. XRD analysis of the sample after reduction did not confirm the reduction into Gd6UO11 but a decomposition of the δ-compound. Preliminary characterizations of these decomposition products are presented.
1965 ◽
Vol 2
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pp. 188-215
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2016 ◽
Vol 704
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pp. 225-234
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2006 ◽
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pp. 325-328
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2010 ◽
Vol 638-642
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pp. 425-430
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2014 ◽
Vol 660
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pp. 249-253
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2016 ◽
Vol 846
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pp. 189-192
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