Simulation of ozonolysis of volatile organic compounds: Effect on flue gas composition

This study shows that the reaction of ozone with various volatile organic compounds (VOC) yields different flue gas composition in terms of the carbon dioxide, oxygen and moisture contents. Steam production and thermal output requirements from a combustion system (i.e., a boiler) may dictate the range of operating conditions, such as the air to fuel mass flow rates. To improve the combustion efficiency in these operating conditions, low temperature plasmas have been used to ionize air and generate ozone as an oxidant for ozonolysis with the VOC. Therefore, this study simulates the reaction mechanism of the ozonolysis of VOC and the effect on the flue gas composition, which affects the combustion efficiency. Simulation results show that residual oxygen in the flue gas reduces, reducing the excess air. Thus, the corresponding efficiency loss through dry flue gas would be reduced. Literature data shows that emissions of alkanes, alkynes and alkenes per unit mass of solid fuel is evident for both coal and biomass, and thus ozonolysis of these VOC would reduce the excess air, improving the combustion efficiency.

Ionization Balance in Low-Temperature Plasmas with Nanosized Dust

Ionization mechanisms in the low-temperature thermal plasma, which contains alkali metal atoms as ionizable component and nanosized dust grains, are studied. In such a plasma, electrons are captured by dust grains, because the work function of grains depends on their sizes, and the electron adsorption rate is more than the thermionic emission rate for nanosized grains. Accordingly, an increase of the dust grain number leads to a decrease in the volume ionization and recombination rates, because they depend on the number density of electrons. At the same time, the role of surface processes in the plasma ionization balance is increased, because the total grain surface is increased. The approximate calculation techniques for low and high grain number densities are proposed. The criterions for approximate calculations are specified.