Field-scale monitoring of nitrate leaching in agriculture: assessment of three methods

Deterioration of groundwater quality due to nitrate loss from intensive agricultural systems can only be mitigated if methods for in-situ monitoring of nitrate leaching under active farmers’ fields are available. In this study, three methods were used in parallel to evaluate their spatial and temporal differences, namely ion-exchange resin-based Self-Integrating Accumulators (SIA), soil coring for extraction of mineral N (Nmin) from 0 to 90 cm in Mid-October (pre-winter) and Mid-February (post-winter), and Suction Cups (SCs) complemented by a HYDRUS 1D model. The monitoring, conducted from 2017 to 2020 in the Gäu Valley in the Swiss Central Plateau, covered four agricultural fields. The crop rotations included grass-clover leys, canola, silage maize and winter cereals. The monthly resolution of SC samples allowed identifying a seasonal pattern, with a nitrate concentration build-up during autumn and peaks in winter, caused by elevated water percolation to deeper soil layers in this period. Using simulated water percolation values, SC concentrations were converted into fluxes. SCs sampled 30% less N-losses on average compared to SIA, which collect also the wide macropore and preferential flows. The difference between Nmin content in autumn and spring was greater than nitrate leaching measured with either SIA or SCs. This observation indicates that autumn Nmin was depleted not only by leaching but also by plant and microbial N uptake and gaseous losses. The positive correlation between autumn Nmin content and leaching fluxes determined by either SCs or SIA suggests autumn Nmin as a useful relative but not absolute indicator for nitrate leaching. In conclusion, all three monitoring techniques are suited to indicate N leaching but represent different transport and cycling processes and vary in spatio-temporal resolution. The choice of monitoring method mainly depends (1) on the project’s goals and financial budget and (2) on the soil conditions. Long-term data, and especially the combination of methods, increase process understanding and generate knowledge beyond a pure methodological comparison.

Effects of grass type on hydraulic response of the three-layer landfill cover system

Soil column tests were conducted to investigate the effects of grass type on water infiltration in a three-layer landfill cover under drying and wetting conditions. Five soil columns were prepared, including one bare, two Bermuda grass-planted and the other two vetiver-planted. During the drying period, the suction of vetiver-planted soil column was the largest, while that of bare case was the lowest. During the wetting period, the infiltration rate shows a bimodal form due to the contrasting hydraulic properties of different soil layers. The infiltration rate of vetiver-planted soil column was the lowest, followed by Bermuda grass-planted and bare cases. Correspondingly, the vetiver-planted soil column retained the maximum suction and the deepest ponding depth during rainfall. This was likely due to the larger leaf area and deeper roots of vetiver than those of Bermuda grass, thus inducing the maximum initial suction by root water uptake before rainfall and reducing the water permeability by root occupations of soil pores. These results show that vetiver is more effective than Bermuda grass to reduce water percolation through the three-layer landfill cover.

LAB-SCALE EXPERIMENTS FOR SOIL CEMENTING THROUGH BIO-CHEMICAL PROCESS

Ureolytic bacteria strains of Bacillus show its ability of calcium carbonate precipitation through metabolic activity. Different studies related to self-healing concrete material were reported associated with the generated calcium carbonate of Bacillus subtilis HU58 metabolism in recent communications. In this paper, recent findings of soil cementing with a combination of such precipitated products were presented. The experiments relied on the lab-scale studies with the use of sand-clay mixture as the controlled soil specimens. Bacillus bacteria and nutrients were mixed to introduce in the sand matrix and then curing in high moisture condition. The composition and morphology of soil specimens were characterized after solidifying by FTIR, XRD, and SEM. Water percolation and mechanical stability for the physicomechanical properties were also tested with the unconventional method. Discussing the relevant results can help to figure out the next experiments in the field of geotechnical engineering. From the perspective of this study, the sustainability factor should be considered to apply this promising technique for soil stabilization and improvement and/or for the formulation of bio-brick as an alternative to sintered clay-based brick. From the perspective of this study, this technique for soil stabilization and improvement and/or for the formulation of bio-brick can be considered a promising sustainable alternative to sintered clay-based brick.

Calcitic-based stones protection by a low-fluorine modified methacrylic coating

Atmospheric pollutants, such as NOx, SO2, and particulate matter, together with water percolation inside the stone pores, represent the main causes of cultural heritage decay. In order to avoid these undesired phenomena, the application of protective coatings represents a reliable solution. In this context, the present study focused on the synthesis of low-fluorine content methacrylic-based (MMA) polymeric resins characterized by seven F atoms (namely F7 monomer) in the lateral chains. Four different percentages (1.0, 2.5, 5.0, and 10.0%) of the present monomer were adopted to obtain a final polymeric structure showing the desired hydrophobicity, processability, and structural and thermal stability (even after accelerated UV aging tests). MMA_F7(1.0) seemed to be the optimal one; therefore, it was further applied onto Candoglia marble. Specifically, the treated substrates showed good surface hydrophobicity, water repellency, and water vapor transpirability. No color variation was observed even after a 1.5-year exposure in a real polluted environment (Monza Cathedral). Interestingly, the application of this coating hindered the atmospheric nitrates penetration inside the stones and, at the same time, it limited the sulfates (gypsum) formation, thus revealing a very promising marbles protection resin.

Man-made disaster on urban area: subsidence and underground salt dissolution in Maceio (Brazil) revealed by remote sensing and numerical modelling

<p>Land subsidence hazard affects many highly populated urban areas of the world as a consequence of natural and/or anthropogenic derived geomechanical rock alterations. Here we exploit the full archive of Synthetic Aperture Radar (SAR data) and present a 16-years history (2004-2020) of surface displacement affecting the federal capital of Maceió (Alagoas, Brazil), where sinkhole formation and fractures on infrastructures have been intensified since early 2018, forcing authorities to relocate the affected residence and pose the building under demolition. The geodetic result shows that precursory deformations were already visible in early 2000’s, reaching in November 2020 a maximum cumulative subsidence of approximately 2 m near the Mundaú lagoon coast. The maximum rate of subsidence is estimated at 27 cm/year. Numerical elastic source modelling proves that the subsidence is associated with localized, deep seated material removal at the location and depth where salt mining is performed. More sophisticated 2D distinct element method highlights the formation of cracks in sedimentary layers that eventually enables strong water percolation from rather superficial aquifers into the deeper underground, with potential increase of material dissolution and erosion. We discuss the accelerating subsidence rates, the influence of severe precipitation events to the aforementioned geological instability and the related dynamic evolution of the subsidence hazard by generating dynamic geohazard maps valuable for further infrastructure risk assessment.</p>

Modeling Subsurface Drainage in Compacted Cultivated Histosols

Reclaiming histosols in Montéregie region, Québec, Canada, increases peat decomposition and compaction rate and decreases the effectiveness of subsurface drainage. The objective of this paper was to use HYDRUS-2D to model the behavior of subsurface drainage systems, in order to evaluate the compaction effect on drain depth and spacing, and to determine the compact layer thickness and saturated hydraulic conductivities (Ksat) resulting in an improvement of subsurface drainage]. The drainage model was calibrated [Nash-Sutcliffe efficiency coefficient (NSE) = 0.958, percent bias (PBIAS) = −0.57%] using Ksat, meteorological data, and matric potential (h) data measured on the project site from June 10 to July 19, 2017. The calibrated and validated model was used to analyze the variation of h values (Δh in cm d−1) as a function of drain spacing (2–7 m) and drain depth (1 and 1.2 m) and to identify the response surface of Δh to various compact layer thickness and Ksat combinations. The results showed that Δh was on average 58% greater below the compact layer than above it and that reducing drain spacing or increasing drain depth does not improve the drainage rate. The analysis of the compact layer thickness and Ksat effect on Δh showed that for a Δh of 40 cm d−1, Ksat actual values in the two uppermost layers should be multiplied by 50 for compact layer thickness varying from 12 to 35 cm. Water percolation in the soil is reduced by the compact layer. Soil management methods for improving Ksat should therefore be better than deepening the drains or and reducing the spacing.

Influence of green’s coconut fibers in the unsaturated behavior of compacted clayey soil

The green coconut’s shell is considered to be waste while it represents most of its volume and weight. The objective of this research was to analyze the influence of the addition of 1% (by weight) of green coconut’s (Cocos nucifera) fibers in the unsaturated behavior of compacted mixtures of clayey soil, with fibers randomly distributed in the soil matrix. Both the pure soil and the mixture were submitted to filter paper tests according to Chandler and Gutierrez (1986) and Marinho (1994), in order to obtain their characteristic curves and verify their differences, using the relation suction-humidity proposed by Chandler, Crilly and Montgomery-Smith (1992) and van Genuchten’s (1980) adjustment method, which was also used to estimate the unsaturated hydraulic conductivity and relative permeability to air and water as functions of the degree of saturation. The results revealed that the addition of fibers provided greater water percolation in the drying path, and greater air flow during wetting. This behavior is a reflection of the greater retention capacity provided by the fibers, which promotes a more gradual change in the degree of saturation, in relation to the ‘pure soil’, which is a very interesting characteristic for applications subject to large variations in humidity.

Summary and Conclusion

A number of well-established physical and mechanical laws are often improperly applied to snow, which is a very particular medium regarding compacity, viscosity, friction, rupture, etc. Snow is described as a changeable granular and porous material, and analyzed using a combination of statistical and deterministic approaches, with the help of the theory of dynamical systems. Specific models are developed for slab, superficial, and full-depth avalanches. The series of successive physical mechanisms responsible for slab avalanche triggering is now perfectly known, involving weak layer collapse and expansion, in which possible healing may abort the whole process. Loose snow avalanches are reminiscent of Bak’s sand pile model, and full-depth avalanches are modeled in terms of snow-water percolation. The specific arrest mechanisms are analyzed. The present analysis should help in taking wise decisions in the face of unexpected situations. The future of snow avalanches is explored in the context of present climate warming.