Interface structure and shear strength of brazed joints between cermets and 45 steel in formed Cu-Zn-Ni-Mn-Si-Mo filler metal

Author(s):  
Chaogang Xue ◽  
Yong Zheng ◽  
Xuepeng Lu ◽  
Xiangyu Xu ◽  
Zishen Han ◽  
...  
2005 ◽  
Vol 502 ◽  
pp. 467-472
Author(s):  
Hui Jie Liu ◽  
Jicai Feng

Vacuum brazing of a TiAl-based alloy to a medium-carbon steel has been carried out at 1173 K for 2-40 min using Ag-Cu-Ti and Ag-Cu-Zn filler metals. The formation phases and interface structure or microstructure of the joints were investigated by SEM, EPMA and XRD, and the strength of the joints was determined by the shear testing method. The experimental results indicate that (1) Ti(Cu,Al)2, Ag(s.s.), Ag-Cu eutectic and TiC phases have occurred in the TiAl/steel joints, and their amount changes with the brazing time; (2) the interface structures of the joints brazed with the Ag-Cu-Ti filler metal is TiAl/Ti(Cu,Al)2+ Ag(s.s.)/Ag(s.s.)+Ti(Cu,Al)2/TiC/steel, while the microstructure of the joints brazed with the Ag-Cu-Zn filler metal is composed of a continuous TiC layer and a mixed zone of Ti(Cu,Al)2, Ag(s.s.) and Ag-Cu eutectic; (3) the shear strength of the joints brazed with the Ag-Cu-Ti filler metal monotonously decreases with increasing brazing time, while the shear strength of the joints brazed with the Ag-Cu-Zn filler metal first rises and then decreases, accordingly an optimum brazing time exists; (4) the maximum shear strengths of the TiAl/steel joints brazed with the Ag-Cu-Ti and Ag-Cu-Zn filler metals are 170 and 190 MPa, respectively.


2017 ◽  
Vol 31 (08) ◽  
pp. 1750082 ◽  
Author(s):  
Peng Wang ◽  
Zeng Gao ◽  
Dongfeng Cheng ◽  
Dongxia Xu ◽  
Jitai Niu

Compared without electroless Ni–P alloy coating on the SiCp/Al composites, the paper describes the effect of Ni–P deposited layer on the microstructure evolution, shear strength, airtightness and fracture behavior of vacuum brazed joints. Void free and compact reaction layers along the 6063Al/Ni–P deposited layer/filler metal interfaces indicated that the joints exhibit high airtightness with He-leakage less than [Formula: see text] [Formula: see text]. Energy Dispersive X-ray Spectroscopy (EDS) analysis showed that the reaction layers mainly included brittle Al–Ni and Al–Cu–Ni intermetallics, where fracture occurred in priority and the shear strength was less than 90 MPa. However, without Ni–P alloy coating, sound joints with high shear strength of 100.1 MPa but low airtightness with He-leakage higher than [Formula: see text] were also obtained at 590[Formula: see text]C for soaking time of 30 min. In this case, a few holes that occurred along the filler metal/SiC particle interface significantly decreased the compactness of the joints. Therefore, according to the requirements in practical applications, suitable choice was provided in this research.


2011 ◽  
Vol 291-294 ◽  
pp. 910-914
Author(s):  
Yang Zhang ◽  
Cha Qin ◽  
Hao Zhu

The ultrasonically brazing of 55 vol.% SiCp/A356 composites in air has been investigated. When the ultrasonic vibration is applied for 0.5s, the oxide layer is still continuous at most places between the filler metal and the composites. The shear strength is only ~30% of that of the base composites. As the ultrasonic action time increases, the oxide film sufficiently disappears in the bond region, and the wetted area between the filler metal and SiC particles increases gradually. As a consequence of this, the shear strength of bonds also increases with the ultrasonically acting time. The maximum value of the shear strength of the bonds reaches 165.5MPa when the ultrasonic acting time increases to 5s, which is similar to the shear strength of the base composites.


Metals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 198 ◽  
Author(s):  
Peng Xue ◽  
Yang Zou ◽  
Peng He ◽  
Yinyin Pei ◽  
Huawei Sun ◽  
...  

The microstructure and properties of a Cu/304 stainless steel dissimilar metal joint brazed with a low silver Ag16.5CuZnSn-xGa-yCe braze filler after aging treatment were investigated. The results indicated that the addition of Ce could reduce the intergranular penetration depth of the filler metal into the stainless steel during the aging process. The minimum penetration depth in the Ag16.5CuZnSn-0.15Ce brazed joint was decreased by 48.8% compared with the Ag16.5CuZnSn brazed joint. Moreover, the shear strength of the brazed joint decreased with aging time while the shear strength of the AgCuZnSn-xGa-yCe joint was still obviously higher than the Ag16.5CuZnSn joint after a 600 h aging treatment. The fracture type of the Ag16.5CuZnSn-xGa-yCe brazed joints before aging begins ductile and turns slightly brittle during the aging process. Compared to all the results, the Ag16.5CuZnSn-2Ga-0.15Ce brazed joints show the best performance and could satisfy the requirements for cost reduction and long-term use.


2005 ◽  
Vol 297-300 ◽  
pp. 2441-2446 ◽  
Author(s):  
Shi Yao Qu ◽  
Zeng Da Zou ◽  
Xin Hong Wang

Shear strength and fracture behavior of Al2O3 matrix ceramic composite brazed joints to carbon steel with Ag-Cu-Ti brazing alloy in flow argon have been studied by means of SEM, EDX and all-purpose testing machine. Results have shown that there is a close relationship between the shear strength and the fracture form of brazed joints. The fracture occurring completely in the composite near the composite/filler metal interface corresponds to the low strength of a joint, and the strength of the joint fractured partially in the composite usually increases with decreasing the proportion of the composite on the fracture surface in the steel side. When the fracture occurs in the reaction layer between the composite and the filler metal, the closer the fractured position comes to the composite/reaction layer interface, the higher the joint strength. The maximum shear strength is obtained when the fracture occurs fully at the interface.


Metals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 896 ◽  
Author(s):  
Duo Dong ◽  
Dongdong Zhu ◽  
Ye Wang ◽  
Gang Wang ◽  
Peng Wu ◽  
...  

Vacuum brazing of TiAl intermetallic alloy to Si3N4 ceramics was performed using Ag-28Cu (wt.%) filler alloy. The brazing joints obtained at different brazing temperatures were studied in this work. The microstructure and the shear strength were analyzed in detail. The results show that the brazed joints could be divided into three regions: AlCu2Ti reaction layer near the Ti-48Al-2Cr-2Nb alloy, a typical Ag-Cu eutectic structure and a thin continuous TiN + Ti5Si3 reaction layer near the Si3N4 ceramics. The microstructure varied as the brazing temperature was increased from 1153 K/15 min to 1193 K/15 min. The shear strength of the joints first increased as the brazing temperature increased from 1153 K to 1173 K, and then decreased. The maximum shear strength reached 105.5 MPa at 1173 K/15 min and the mechanism was discussed.


2014 ◽  
Vol 7 (2) ◽  
pp. 103-144
Author(s):  
Omar Saad Salih

Furnace brazing was carried out to produce joints between two different materials, Oxygen Free High Conductivity Copper [OFHC] type ISO C10300 and silicon steel (electric steel) type ASTM 36F145 by using two groups of filler metals were selected in this research, silver group type DIN L-Ag20Cd and copper group type AWS BCuP-1 with using flux type AWS FB3-A to remove oxide and protect the welding joint.The brazing temperature for both filler was 790°C and 940°C respectively above liquidus temperature of them, then soaking at different time (10, 20,30,40,50, and 60min.) for each filler metal. The microstructures of cross section area of joints were revealed in optical microscope shows presence of different reaction in the brazed area.The maximum double shear strength of dissimilar brazed joints was 47MPa by using filler metal AWS BCuP-1 at 30min. soaking time, while using filler metal DIN L-Ag20Cd give rice in double shear strength to 98MPa at 30min. soaking time due to better coalescence of the mating surfaces .The occurrence of solid solution and different types of intermetallic compounds such as Cu5Si, Fe3Zn10, FeZn10, Cu5Zn6, CuZn, CdCu2, Cd3Cd4, Cd3Cu, Cu3P,and α-Fe that is responsible for joint strength has been detected by X-ray diffraction inspection.


2021 ◽  
Vol 2083 (2) ◽  
pp. 022086
Author(s):  
Xiupeng Li ◽  
Yunyue Li ◽  
Sujuan Zhong ◽  
Yuanxun Shen ◽  
Weimin Long ◽  
...  

Abstract In this paper, a new type of AlSiMgCuNiAg filler metal was developed. The solidus temperature of the filler metal is 509.1°C and the liquidus temperature is 531.3°C. The filler metal has a good wetting and spreading effect on the surface of 6061 aluminum alloy. The CuAl2 phase in the brazing seam was greatly aggregated after brazed, while the CuAl2 phase was reduced and Mg2Si strengthening phase was formed when the brazed joints with heat treatment. The average shear strength of the brazed joint without heat treatment was 47.1MPa, and the average shear strength of the brazed joint with heat treatment reached to 108.7Mpa. The strength of the brazed joint with heat treatment was increased by about 131% relative to the strength of the brazed joint without heat treatment.


2019 ◽  
Vol 91 (10) ◽  
pp. 35-41 ◽  
Author(s):  
Li Hong ◽  
Liu Xuan ◽  
Huang Haixin

Reliable ceramics/metal joints have an extensive application in the aerospace and biomedical area. However, ZrO2ceramic has not been investigated systematically compared to the Si3N4and Al2O3ceramic. Therefore, successful brazing of ZrO2ceramic and Ti-6A-4V alloy was achieved by using a binary active Ti-28Ni filler metal in this paper. The effect of holding time on the microstructure of ZrO2 ceramic/filler metal interface and mechanical properties of brazed joints was investigated. The results indicated that the representative interfacial microstructure was ZrO2ceramic/Ti2O/Ni2Ti4O/Ti-rich phase/Ti2Ni+α-Ti. With the increase of holding time, the thickness of Ti-rich layer in the interface of ZrO2/Ti-6Al-4Vjoint decreased obviously due to the diffusion of Ti atoms. Substantial brittle intermetallic compounds Ti2Ni and Ni2Ti4O were formed in the joint, which were detrimental to the mechanical properties of the brazed joints. The maximum shear strength of joint was 112.7 MPa when brazed at 1060 °C for 10 min.


2019 ◽  
Vol 9 (6) ◽  
pp. 1094
Author(s):  
Shubin Liu ◽  
Ikuo Shohji ◽  
Makoto Iioka ◽  
Anna Hashimoto ◽  
Junichiro Hirohashi ◽  
...  

A Ni-P plated layer of 20 μm thickness containing 11 wt.% P was formed on the surface of a stainless steel (SUS304) plate by electroplating. The microstructure and joint strength of the brazed joint with the electroplated Ni-11P layer were investigated. The results indicated that the filler metal was homogeneously distributed between the SUS304 plates and no voids or flaws formed in the brazed filler zone. Fe-Ni-Cr solid solutions were formed at the brazed interface. Moreover, P was mainly concentrated in such brazed filler zone to form P-containing phases. The average shear strength of the brazed joints was determined to be 47.3 MPa. The results demonstrated that the brazing of SUS304 plates using the electroplated Ni-11P layer as the filler metal was successfully realized.


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