Free Particle, Wave Packet and Dynamics, Quantum Dots, Defects and Traps
This chapter continues with a study of the time independent Schrödinger equation and seeks to contrast the quantum behavior of a free particle with that of a particle localized in a potential quantum well. A free particle can exist over all space or can be localized in a wave package. The wave packet is a coherent superposition of the plane waves that make up the wave function that localizes the particle because of constructive and destructive interference. The wave packet spreads out in time because the waves leading to constructive interference get out of phase. In Chapter 2, the particle was localized by a quadratic potential energy. Here, the potentials are described as piecewise constant. The approach is based on assuming a one-dimensional space, x, which is relevant to many problems in the laboratory. The solution is easily generalized to higher dimensions (x-y or x-y-z), but the physics remains the same. The objective is to understand the shape of the eigenfunctions in space and to be able to relate this to the probability density of locating the particle, as well as understanding the relevance of these systems to today’s technology.