scholarly journals Extrusion Based 3D Printing of Sustainable Biocomposites from Biocarbon and Poly(trimethylene terephthalate)

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4164
Author(s):  
Elizabeth Diederichs ◽  
Maisyn Picard ◽  
Boon Peng Chang ◽  
Manjusri Misra ◽  
Amar Mohanty

Three-dimensional (3D) printing manufactures intricate computer aided designs without time and resource spent for mold creation. The rapid growth of this industry has led to its extensive use in the automotive, biomedical, and electrical industries. In this work, biobased poly(trimethylene terephthalate) (PTT) blends were combined with pyrolyzed biomass to create sustainable and novel printing materials. The Miscanthus biocarbon (BC), generated from pyrolysis at 650 °C, was combined with an optimized PTT blend at 5 and 10 wt % to generate filaments for extrusion 3D printing. Samples were printed and analyzed according to their thermal, mechanical, and morphological properties. Although there were no significant differences seen in the mechanical properties between the two BC composites, the optimal quantity of BC was 5 wt % based upon dimensional stability, ease of printing, and surface finish. These printable materials show great promise for implementation into customizable, non-structural components in the electrical and automotive industries.

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2950
Author(s):  
Hongwei Song ◽  
Xinle Li

The most active research area is nanotechnology in cementitious composites, which has a wide range of applications and has achieved popularity over the last three decades. Nanoparticles (NPs) have emerged as possible materials to be used in the field of civil engineering. Previous research has concentrated on evaluating the effect of different NPs in cementitious materials to alter material characteristics. In order to provide a broad understanding of how nanomaterials (NMs) can be used, this paper critically evaluates previous research on the influence of rheology, mechanical properties, durability, 3D printing, and microstructural performance on cementitious materials. The flow properties of fresh cementitious composites can be measured using rheology and slump. Mechanical properties such as compressive, flexural, and split tensile strength reveal hardened properties. The necessary tests for determining a NM’s durability in concrete are shrinkage, pore structure and porosity, and permeability. The advent of modern 3D printing technologies is suitable for structural printing, such as contour crafting and binder jetting. Three-dimensional (3D) printing has opened up new avenues for the building and construction industry to become more digital. Regardless of the material science, a range of problems must be tackled, including developing smart cementitious composites suitable for 3D structural printing. According to the scanning electron microscopy results, the addition of NMs to cementitious materials results in a denser and improved microstructure with more hydration products. This paper provides valuable information and details about the rheology, mechanical properties, durability, 3D printing, and microstructural performance of cementitious materials with NMs and encourages further research.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1708
Author(s):  
Wenqiang Hua ◽  
Qilang Lin ◽  
Bo Qu ◽  
Yanyu Zheng ◽  
Xiaoying Liu ◽  
...  

Photosensitive resins used in three-dimensional (3D) printing are characterized by high forming precision and fast processing speed; however, they often possess poor mechanical properties and heat resistance. In this study, we report a photocurable bismaleimide ink with excellent comprehensive performance for stereolithography (SLA) 3D printing. First, the main chain of bismaleimide with an amino group (BDM) was synthesized, and then, the glycidyl methacrylate was grafted to the amino group to obtain the bismaleimide oligomer with an unsaturated double bond. The oligomers were combined with reaction diluents and photo-initiators to form photocurable inks that can be used for SLA 3D printing. The viscosity and curing behavior of the inks were studied, and the mechanical properties and heat resistance were tested. The tensile strength of 3D-printed samples based on BDM inks could reach 72.6 MPa (166% of that of commercial inks), glass transition temperature could reach 155 °C (205% of that of commercial inks), and energy storage modulus was 3625 MPa at 35 °C (327% of that of commercial inks). The maximum values of T-5%, T-50%, and Tmax of the 3D samples printed by BDM inks reached 351.5, 449.6, and 451.9 °C, respectively. These photocured BDM inks can be used to produce complex structural components and models with excellent mechanical and thermal properties, such as car parts, building models, and pipes.


Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2456
Author(s):  
Demei Lee ◽  
Guan-Yu Wu

Three-dimensional (3D) printing is a manufacturing technology which creates three-dimensional objects layer-by-layer or drop-by-drop with minimal material waste. Despite the fact that 3D printing is a versatile and adaptable process and has advantages in establishing complex and net-shaped structures over conventional manufacturing methods, the challenge remains in identifying the optimal parameters for the 3D printing process. This study investigated the influence of processing parameters on the mechanical properties of Fused Deposition Modelling (FDM)-printed carbon fiber-filled polylactide (CFR-PLA) composites by employing an orthogonal array model. After printing, the tensile and impact strengths of the printed composites were measured, and the effects of different parameters on these strengths were examined. The experimental results indicate that 3D-printed CFR-PLA showed a rougher surface morphology than virgin PLA. For the variables selected in this analysis, bed temperature was identified as the most influential parameter on the tensile strength of CFR-PLA-printed parts, while bed temperature and print orientation were the key parameters affecting the impact strengths of printed composites. The 45° orientation printed parts also showed superior mechanical strengths than the 90° printed parts.


Author(s):  
Piyush Chohan ◽  
Aniket Yadav ◽  
Ranvijay Kumar ◽  
Raman Kumar ◽  
Jasgurpreet Singh Chohan

Background: Three dimensional (3D) printing is emerging technology, capable of manufacturing a solid layer by layer. With the advancements of materials for 3D printing, this technology is applicable in almost every sector. But in accordance with the product requirements we need to modify the mechanical properties of material. To achieve good surface finish we require coating of filament. For this purpose an apparatus is designed for coating of material over a filament, which is capable of coating filaments uniformly and with automated process. Objective: The objective of present invention is directed to a filament feeding device for applying uniform coating on a filament in order to make 3D solid objects with good quality finishing, thereby eliminating the chances of strains and imperfect coating on the filament. Methods: The present invention relates to a filament feeding device, comprising a container equipped within the device for storing a chemical solution in a liquefied form, an inlet port fabricated on the container for inserting a filament inside the container, plurality of relief valves placed at a bottom portion of the container for controlling the leakage of the filaments during insertion of the filaments. A stepper motor in association with a blade equipped within the container to rotate the main extruder of a 3D printer, and an outlet port designed opposite to the inlet port for discharging the filament from the container for 3D printing of the filament in order to manufacture the solid object. Results: The apparatus makes it easy for coating and coloration of materials to make the reinforced composite filaments. As this apparatus provides uniform coating of material on the filaments, the product printed by filaments have good surface finish. Conclusion: The proposed method can reduce coating time and printing time. This work provides meaningful implication to researchers who are doing research in the domain of additive manufacturing.


2011 ◽  
Vol 701 ◽  
pp. 1-8
Author(s):  
Rupinder Singh

Three dimensional printing (3DP) as rapid casting (RC) solutions has transformed over centuries from black art to science, but the metallurgical impinge on the process responsible for change in mechanical properties (like: surface finish, hardness, dimensional stability etc.) are still disputed. The purpose of the present research paper is to review metallurgical affect of 3DP based RC solution. The result of study suggests that prominent reason found to be responsible for improving the mechanical properties of RC is control of heat transfer rate while solidification (thus reducing dendrite formation).


2021 ◽  
Vol 11 (15) ◽  
pp. 6835
Author(s):  
Sang-U Bae ◽  
Birm-June Kim

Photopolymer composites filled with cellulose nanocrystal (CNC) and/or inorganic nanofillers were fabricated by using digital light processing (DLP) 3D printing. To investigate the effects of different CNC lyophilization concentrations and behaviors of CNC particles in the photopolymer composites, morphological and mechanical properties were analyzed. CNC loading levels affected the morphological and mechanical properties of the filled composites. Better CNC dispersion was seen at a lower lyophilization concentration, and the highest mechanical strength was observed in the 0.25 wt% CNC-filled composite. Furthermore, nano-precipitated calcium carbonate (nano-PCC) and nanoclay were added to photocurable resins, and then the effect of inorganic nanofillers on the morphological and mechanical properties of the composites were evaluated. By analyzing the morphological properties, the stress transfer mechanism of nano-PCC and nanoclay in the photopolymer composites was identified and related models were presented. These supported the improved mechanical strength of the composites filled with CNC, nano-PCC, and nanoclay. This study suggested a new approach using wood-derived cellulose nanomaterials and inorganic nanofillers as effective fillers for DLP 3D printing.


Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1912
Author(s):  
Denesh Mohan ◽  
Zee Khai Teong ◽  
Mohd Shaiful Sajab ◽  
Nur Hidayatul Nazirah Kamarudin ◽  
Hatika Kaco

The tendency to use cellulose fibrils for direct ink writing (DIW) of three-dimensional (3D) printing has been growing extensively due to their advantageous mechanical properties. However, retaining cellulose in its fibrillated forms after the printing process has always been a challenge. In this study, cellulose macrofibrils (CMFs) from oil palm empty fruit bunch (OPEFB) fibers were partially dissolved for consistent viscosity needed for DIW 3D printing. The printed CMF structure obtained from optimized printing profiles (volumetric flow rate, Qv = 9.58 mm/s; print speed, v = 20 mm/s), exhibited excellent mechanical properties (tensile strength of 66 MPa, Young’s modulus of 2.16 GPa, and elongation of 8.76%). The remarkable structural and morphological effects of the intact cellulose fibrils show a homogeneous distribution with synthesized precipitated calcium carbonate (CaCO3) nanoparticles. The shear-aligned CMF/CaCO3 printed composite exhibited a sustained therapeutic drug release profile that can reduce rapid release that has adverse effects on healthy cells. In comparison with the initial burst release of 5-fluorouracil (5-FU) by CaCO3, the controlled release of 5-fluorouracil can be varied (48 to 75%) with the composition of CMF/CaCO3 allowing efficient release over time.


2014 ◽  
Vol 1 (4) ◽  
pp. 811-835 ◽  
Author(s):  
Lucas S. Osborn

The confluence of three-dimensional printing, three-dimensional scanning, and the Internet will erode the dividing line between the physical and the digital worlds and will bring millions of laypeople into intimate contact with the full spectrum of intellectual property laws. One of the areas most affected by 3D printers will be three-dimensional art. This Article analyzes several ways in which 3D printing technology will affect the creation, delivery, and consumption of art. Not only does 3D printing offer great promise for creative works, but it also presents a problem of piracy that may accompany the digitization of three-dimensional works. As 3D printing technology’s relationship to intellectual property law is largely unexplored, this Article explores foundational issues regarding how copyright law applies to 3D printing technology, laying the groundwork upon which further analysis of 3D printing’s effects on copyright law may be built.


Author(s):  
Mohammad M. Hossain ◽  
Chandra Nath ◽  
Thomas M. Tucker ◽  
Richard W. Vuduc ◽  
Thomas R. Kurfess

Machining is one of the major manufacturing methods having very wide applications in industries. Unlike layer-by-layer additive three-dimensional (3D) printing technology, the lack of an easy and intuitive programmability in conventional toolpath planning approach in machining leads to significantly higher manufacturing cost for direct computer numerical control (CNC)-based prototyping (i.e., subtractive 3D printing). In standard computer-aided manufacturing (CAM) packages, general use of B-rep (boundary representation) and non-uniform rational basis spline (NURBS)-based representations of the computer-aided design (CAD) interfaces make core computations of tool trajectories generation process, such as surface offsetting, difficult. In this work, the problem of efficient generation of freeform surface offsets is addressed with a novel volumetric (voxel) representation. It presents an image filter-based offsetting algorithm, which leverages the parallel computing engines on modern graphics processor unit (GPU). The compact voxel data representation and the proposed computational acceleration on GPU together are capable to process voxel offsetting at four-fold higher resolution in interactive CAM application. Additionally, in order to further accelerate the offset computation, the problem of offsetting with a large distance is decomposed into successive offsetting using smaller distances. The performance trade-offs between accuracy and computation time of the offset algorithms are thoroughly analyzed. The developed GPU implementation of the offsetting algorithm is found to be robust in computation, and demonstrates a 50-fold speedup on single graphics card (NVIDIA GTX780Ti) relative to prior best-performing algorithms developed for multicores central processing units (CPU). The proposed offsetting approach has been validated for a variety of complex parts produced on different multi-axis CNC machine tools including turning, milling, and compound turning-milling.


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