ion permeability
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2022 ◽  
Vol 1048 ◽  
pp. 311-320
Author(s):  
Tarun Gehlot ◽  
Suresh Singh Sankhla ◽  
Sangeeta Parihar

In this study conventional concrete of M40 grade developed with diverse water binder ratio and fixed optimum dosage of 30% mineral admixture fly ash and GGBS with weight of cement .Compression test has been conducted on cube samples and Rapid Chloride permeability test (RCPT) are conducted on cylindrical specimens to acknowledge durability parameter. Compression test results has been enhanced with replacement of supplementary cementitious materials and chloride ion permeability has been reduced with substitution of fly ash and GGBS .incremental of water binder ratio also reduce the permeability value however compression value increased


Langmuir ◽  
2021 ◽  
Author(s):  
Evelyne Deplazes ◽  
Beatriu Domingo Tafalla ◽  
Christopher Murphy ◽  
Jacqueline White ◽  
Charles G. Cranfield ◽  
...  

2021 ◽  
Vol 11 (21) ◽  
pp. 10137
Author(s):  
Limin Lu ◽  
Shaohua Wu ◽  
Yuwen Qin ◽  
Guanglin Yuan ◽  
Qingli Zhao ◽  
...  

Chloride ion penetration frequently leads to steel corrosion and reduces the durability of reinforced concrete. Although previous studies have investigated the chloride ion permeability of some fiber concrete, the chloride ion permeability of the basalt fiber reinforced concrete (BFRC) has not been widely investigated. Considering that BFRC may be subjected to various exposure environments, this paper focused on exploring the chloride ion permeability of BFRC under the coupling effect of elevated temperatures and compression. Results demonstrated that the chloride ion content in concrete increased linearly with temperature. After exposure to different elevated temperatures, the chloride ion content in BFRC varied greatly with increasing stress. The compressive stress ratio threshold for the chloride ion penetration was measured. A calculation model of BFRC chloride ion diffusion coefficient under the coupling effect of elevated temperatures and mechanical damage (loading test) was proposed.


2021 ◽  
Vol 22 (20) ◽  
pp. 10998
Author(s):  
Cédric Vallée ◽  
Brendan Howlin ◽  
Rebecca Lewis

The Epithelial Sodium Channel/Degenerin (ENaC/DEG) family is a superfamily of sodium-selective channels that play diverse and important physiological roles in a wide variety of animal species. Despite their differences, they share a high homology in the pore region in which the ion discrimination takes place. Although ion selectivity has been studied for decades, the mechanisms underlying this selectivity for trimeric channels, and particularly for the ENaC/DEG family, are still poorly understood. This systematic review follows PRISMA guidelines and aims to determine the main components that govern ion selectivity in the ENaC/DEG family. In total, 27 papers from three online databases were included according to specific exclusion and inclusion criteria. It was found that the G/SxS selectivity filter (glycine/serine, non-conserved residue, serine) and other well conserved residues play a crucial role in ion selectivity. Depending on the ion type, residues with different properties are involved in ion permeability. For lithium against sodium, aromatic residues upstream of the selectivity filter seem to be important, whereas for sodium against potassium, negatively charged residues downstream of the selectivity filter seem to be important. This review provides new perspectives for further studies to unravel the mechanisms of ion selectivity.


2021 ◽  
Vol 2021 ◽  
pp. 1-3
Author(s):  
Carlos E. Duran ◽  
Mayra Estacio ◽  
Fredy Lozano ◽  
Esteban Echeverri ◽  
Maria Juliana Riascos ◽  
...  

Case Presentation. Distal renal tubular acidosis (dRTA) is characterized by impaired hydrogen ion secretion in the distal nephron resulting either from decreased net activity of the proton pump or from increased luminal membrane hydrogen ion permeability. Typical complications of dRTA include severe hypokalemia, normal anion gap metabolic acidosis, nephrolithiasis, and nephrocalcinosis. The patient is a 25-year-old woman in immediate puerperium with hypokalemia leading to paralysis, and the laboratory findings in this patients were concerning for dRTA. It is rare to encounter this entity during pregnancy, and the impact of this pathology is unknown.


Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 932
Author(s):  
Huu-Bang Tran ◽  
Van-Bach Le ◽  
Vu To-Anh Phan

This paper presents the experimental results of the production of Nano-SiO2 (NS) from rice husk ash (RHA) and the engineering properties of High Strength Concrete (HSC) containing various NS contents. Firstly, the mesoporous silica nanoparticles were effectively modulated from RHA using NaOH solution, and subsequently precipitated with HCl solution until the pH value reached 3. The optimum synthesis for the manufacture of SiO2 nanoparticles in the weight ratio of RHA/NaOH was 1:2.4, and the product was calcined at 550 °C for 2 h. The EDX, XRD, SEM, TEM, FT-IR, and BET techniques were used to characterize the NS products. Results revealed that the characteristics of the obtained NS were satisfactory for civil engineering materials. Secondly, the HSC was manufactured with the aforementioned NS contents. NS particles were added to HSC at various replacements of 0, 0.5, 1.0, 1.5, 2.0, and 2.5% by the mass of the binder. The water-to-binder ratio was remained at 0.3 for all mixes. The specimens were cured for 3, 7, 28, 25 days under 25 ± 2 °C and a relative humidity of 95% before testing compressive and flexural strengths. Chloride ion permeability was investigated at 28 and 56 days. Results indicated that the addition of NS dramatically enhanced compressive strength, flexural strength, chloride ion resistance, and reduced chloride ion permeability compared to control concrete. The optimal NS content was found at 1.5%, which yielded the highest strength and lowest chloride ion permeability. Next, the development of flexural and compressive strengths with an age curing of 3–28 days can be analytically described by a logarithmic equation with R2 ≥ 0.74. The ACI code was used, and the compressive strength at t-day was determined based on 28 days with R2 ≥ 0.95. The study is expected to solve the redundancy of waste RHA in southern Vietnam by making RHA a helpful additive when producing high-strength concrete and contributing meaningfully to a sustainable environment.


Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 145
Author(s):  
Kseniia Tsygurina ◽  
Olesya Rybalkina ◽  
Konstantin Sabbatovskiy ◽  
Evgeniy Kirichenko ◽  
Vladimir Sobolev ◽  
...  

Ion exchange membranes covered with layers of polyelectrolytes of alternating charges are characterized by very high monovalent selectivity. This allows the use of such membranes for electrodialytic fractionation of multicomponent solutions. However, the very existence of the boundary at which differently charged layers come in contact can hinder a membrane’s effectiveness by limiting its ion permeability, raising levels of H+ and OH− ions (thus shifting the pH) and increasing the electrical resistance of the membrane, which leads to increased energy consumption. To test how these properties would be changed, we created cheap layer-by-layer-modified membranes based on the heterogeneous MK-40 membrane, on which we adsorbed layers of polyallylamine and sulfonated polystyrene. We created samples with 3, 4, and 5 layers of polyelectrolytes and characterized them. We showed that the application of layers did not decrease the efficiency of the membrane, since the electrical resistance of the modified samples, which increased after application of the first oppositely charged layer, declined with the application of the following layers and became comparable to that of the substrate, while their limiting current density was higher and the shift of pH of treated solution was low in magnitude and comparable with that of the substrate membrane.


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