Effects of Repeated Heating on Fatty Acid Composition of Plant-Based Cooking Oils

Several polyunsaturated fatty acids are considered to have beneficial health effects, while saturated fatty acids and industrial trans fatty acids (TFAs) are linked to negative health consequences. Given the increased formation of TFAs during heating, many studies already investigated compositional changes in oils after prolonged heating or at extremely high temperatures. In contrast, our aim was to measure changes in fatty acid composition and in some health-related indices in edible oils after short-time heating that resembles the conventional household use. Potatoes were fried in palm, rapeseed, soybean, sunflower and extra virgin olive oils at 180 °C for 5 min, and samples were collected from fresh oils and after 1, 5 and 10 consecutive heating sequences. Regardless of the type of oil, the highest linoleic acid and alpha-linolenic acid values were measured in the fresh samples, whereas significantly lower values were detected in almost all samples following the heating sequences. In contrast, the lowest levels of TFAs were detected in the fresh oils, while their values significantly increased in almost all samples during heating. Indices of atherogenicity and thrombogenicity were also significantly higher in these oils after heating. The present data indicate that prolonged or repeated heating of vegetable oils should be avoided; however, the type of oil has a greater effect on the changes of health-related indices than the number of heating sequences.

High-Temperature Measurement of a Fiber Probe Sensor Based on the Michelson Interferometer

In this paper, a fiber probe high-temperature sensor based on the Michelson Interferometer (MI) is proposed and experimentally verified. We used a fiber splicing machine to fabricate a taper of the single-mode fiber (SMF) end. The high order modes were excited at the taper, so that different modes were transmitted forward in the fiber and reflected by the end face of the fiber and then recoupled back to the fiber core to form MI. For comparison, we also coated a thin gold film on the fiber end to improve the reflectivity, and the reflection intensity was improved by 16 dB. The experimental results showed that the temperature sensitivity at 1506 nm was 80 pm/°C (100 °C~450 °C) and 109 pm/°C (450 °C~900 °C). The repeated heating and cooling processes showed that the MI structure had good stability at a temperature up to 900 °C. This fiber probe sensor has the advantages of a small size, simple structure, easy manufacturing, good stability, and broad application prospects in industrial and other environments.

Dual Thermo- and Photo-Responsive Micelles Based on Azobenzene-Containing Random Copolymer

Amphiphilic random copolymer poly(methacrylamido-azobenzene)-ran-poly(2-hydroxyethylacrylate) (PMAAAB-ran-PHEA) was synthesized via hydrolysis of poly(methacrylamido-azobenzene)-ran-poly[2-((2′-tetrahydropyranyl)oxy)ethylacrylate] (PMAAAB-ran-P(THP-HEA)), which was prepared by conventional radical polymerization. PMAAAB-ran-PHEA micelles were then prepared via dialysis method against water with DMF as solvent. The structure, morphology, size, and low critical solution temperature (LCST) of PMAAAB-ran-PHEA and its micelles were determined by 1H-NMR, GPC, TEM, and DLS. The thermo- and photo-responsive behaviors of the resulting polymer micelles were investigated with Nile red as a fluorescence probe. The results showed that PMAAAB-ran-PHEA micelles were porous or bowl-shaped and its size was 135–150 nm, and its LCST was 55 °C when FMAAAB of the random copolymer was 0.5351; the hydrophobicity of the micellar core was changed reversibly under the irradiation of UV light and visible light without release of Nile red or disruption of micelles; the size and solubilization capacity of the micelles were dependent on temperature, and Nile red would migrate for many times between the water phase and the micelles, and finally increasingly accumulated during the repeated heating and cooling processes.

Creation of stable water-free antibody based protein liquids

Antibodies represent highly specific and high binding affinity biomolecular recognition elements for diagnostic assays, biosensors, and therapeutics, but are sensitive to denaturation and degradation. Consequently, the combination of existing in a hydrated state with a large and complex biomolecular structure results in loss of antibody-antigen binding, limited shelf-life, and decreased sensor response over time and under non-optimal conditions. The development and use of water-free protein liquids has led to stabilization of labile biomolecules, solvents for biotransformation reactions, and formation of new bio-composites with incompatible materials. Here, we exploit the polycationic nature of modified antibodies and their ability to form ion pairs for the conversion of primary Immunoglobulin G antibodies into stable protein liquids that retained more than 60% binding activity after repeated heating up to 125 °C, and demonstrate compatibility with thermoplastics.

Lipid Oxidation Products on Inflammation-Mediated Hypertension and Atherosclerosis: A Mini Review

Cardiovascular diseases such as hypertension and atherosclerosis are the common causes of mortality in developed and developing countries. Repeated heating of the dietary oil is a common practice to reduce cost during food preparation. When the cooking oil is heated at high temperatures, production of free radicals augments the oxidative degradation of lipids and depletes the natural antioxidant contents of the cooking oil. Chronic intake of foods prepared using reheated oil could impair antioxidant capacity, leading to oxidative stress and inflammation. This review aims to summarize the current evidence of lipid oxidation products on hypertension and atherosclerosis via inflammatory pathway. In particular, toxic lipid oxidation products such as malondialdehyde and 4-hydroxy-2-nonenal are taken into account. Understanding the signaling pathways underlying the pathology associated with the lipid oxidation-derived aldehydes may be useful to develop therapeutic strategies for the prevention of inflammatory-related cardiovascular complications.

Calibrating Antarctic ice sheet mass loss due to millennial-scale ocean thermal forcing

Throughout the Late Pleistocene, millennial-scale cycles in the rate of poleward heat transport resulted in repeated heating and cooling of the Southern Ocean1. Ice sheet models2 suggest that this variation in Southern Ocean temperature can force fluctuations in the mass of the Antarctic ice sheet that transiently impact sea level by up to 15 meters. However, current geologic evidence for Antarctic ice response to this ocean thermal forcing is unable to calibrate these models, leaving large uncertainty in how Antarctica contributes to sea level on millennial timescales. Here we present a >100kyr archive of East Antarctic Ice Sheet response to Late Pleistocene millennial-scale climate cycles recorded by transitions from opal to calcite in subglacial precipitates. 234U-230Th dates for two precipitates define a time series for 32 mineralogic transitions that match Antarctic climate fluctuations, with precipitation of opal during cold periods and calcite during warm periods. Geochemical evidence indicates opal precipitation via cryoconcentration of silica in subglacial water and calcite precipitation from the admixture of meltwater flushed from the ice sheet interior. These freeze-flush cycles represent changes in subglacial hydrologic-connectivity driven by ice sheet thickness response to Southern Ocean temperature oscillations around the Ross Embayment. Changes in Ross Embayment ice mass require high ocean-ice heat exchange2, and would occur only after retreat of the West Antarctic Ice Sheet3 and large portions of the East Antarctic Ice sheet margin4. These results point to high Antarctic ice sheet sensitivity to millennial-scale ocean thermal forcing throughout the Late Pleistocene, and when combined with modeling results2, predict that an Antarctic ice volume of at least 2–5 meters sea level equivalent is vulnerable to millennial-scale climate forcing.

Microstructure of Additive Manufactured Ti6Al4V by Electron Beam Melting

The electron beam melting-printed Ti6Al4V shows a great potential application for orthopedic implants and aerospace in recent years. A systematic study on the microstructure of additive manufactured Ti6Al4V by electron beam melting both parallel to and perpendicular to the building directions (Z axis) is presented in the present investigation. The results showed that the microstructure of the alloy was α lamina with HCP structure and β bar with BCC structure. The original β phase grew as columnar crystal along the direction of construction, showing an equiaxial shape in the cross section, numerous small α lamellae block the original β phase, and presenting a cluster distribution on the original β grain boundary, and a basket-like distribution in the original β grain. This may be due to the rapid cooling of the small pool after melting, the repeated heating of the subsequent constructed layer on the formed layer, and the subsequent limited vacuum cooling, resulting in the formation of the micro morphology, which leads to the original β grain boundaries broken, and the formation of a distinctive basket or widmanstatten structure [1, 2]. In addition, XRD results indicated that there was α′ martensite, part of which has been decomposes into α phases and β phases, SEM and TEM experiments also proved this. Of note is that random distribution dislocation was observed in TEM. Using EBSD results, and it may be understand that the sample build direction was parallel to [0001] crystal orientation and build plane parallel to (1210) and (1100) crystal facets.

Study of isothermal decomposition of austenite using methods of mathematical modeling

The capabilities of the numerical simulation of technological processes are limited by the accuracy and efficiency of determining the properties of materials which continuously change with repeated heating and cooling. The parameters of structural transformations are the principal factors affecting the properties of alloyed steels. We present a method for determining the parameters of formulas describing C-shaped curves of experimental diagrams of isothermal decomposition of austenite. The proposed approach makes it possible to reconstruct the entire C-shaped curve using a relatively small fragment near the «nose» (by three points). Joint processing of a series of curves provided determination of the parameters of ferritic, pearlitic and bainitic transformation kinetics. However, it is important to take into account the features of the diffusion decomposition of austenite. For example, ferrite and pearlite are formed in overlapping temperature ranges and have similar mechanical properties, but their combining into a single ferrite-pearlite structure complicates the construction of a mathematical model of transformation. The bainitic transformation has a transient character from diffusion to diffusionless one. As for the transformation temperature range, the limiting degree is a function of temperature (as in the case of martensitic transformation). It was shown that for ferrite-pearlite transformation the best results are obtained by the Kolmogorov – Avrami equation, and for the bainitic one — by the Austin – Rickett equation modified with allowance for an incomplete transformation.

Bowl Surface Laser Forming Process of Stainless Steel Composite Plate

In this paper, the three-dimensional bowl surface was obtained by reasonably planning the radial heating path by taking the laser as the heat source and the stainless steel composite plate (06Cr19Ni10/1Cr17Mn6Ni5N/06Cr19Ni10) as the research object, and the forming process of the three-dimensional bowl surface was studied. It was found that the target surface bending forming obtained by inside-outside symmetric scanning strategy (Strategy d) had the highest accuracy. The plate deformation increased with the increase of laser power (P), increased then decreased with the increase of heating line length (L), and decreased with the increase of scanning speed (V). Moreover, the deformation was approximately linear with the number of repeated heating (N), with the optimal process conditions of P = 500W, V = 10 mm/s, L = 20 mm, N = 7. A three-dimensional thermodynamic coupling model of a three-layer composite plate was established and verified experimentally.