In order to study the fracture ability classification of rock mass under the cracking action of supercritical CO2 phase transition, based on the classification theory of rock mass in blasting engineering, an analytic hierarchy process (AHP)-entropy weight method (EWM) and the cloud model classification method for rock mass cracking under CO2 phase transformation are proposed. In this method, rock density, rock tensile strength, rock wave impedance, and rock mass integrity coefficient are used as the factors to determine the level of rock mass fracturing, and the evaluation index system of rock mass fracturing is established. Through this evaluation method, the rock mass in a reconstruction project section of Nyingchi, Tibet, is classified and evaluated. The results present that this new classification method of rock mass fracture ability uses AHP–EWM to carry out the weight distribution of the classification index. In addition, it is combined with the cloud model for the classification division, overcoming the traditional classification method fixed with appraisal pattern flaw. Therefore, it has validity and feasibility. According to the characteristics of fracture ability, the rock masses in the area to be rebuilt on the Tibet Highway are divided into grade II, grade III, and grade IV, which provides scientific guidance for the construction of the project.