Light propagation, coefficient attenuation, and the depth of one optical depth in different water types

The ocean color satellite can only sense a water column up to one optical depth. However, literatur regarding the depth of one optical depth is very limited to none. This study aimed to determine light propagation, attenuation coefficient (Kd), and the depth of one optical depth in different water types. We used in situ data of downwelling irradiance (Ed) with depths taken using the instrument of submersible marine environmental radiometer (MER) in the northeastern gulf of mexico (NEGOM) in April 2000. We also used SeaWiFS data such as water leaving radience (Lw ), remote sensing refectance (Rrs), and chlorophyll-a concentration (Chla). The results showed that the light propagation pattern generally decreased with increasing depth. The reduction in light intensity with depth was very strong in the red wavelengths, lower in the green wavelengths, and the lowest in the blue wavelengths. In contrast, Kd values were generally found the lowest at the blue wavelengths, slightly increase at the purple and green wavelengths, and the highest at the red wavelengths. The depth of one optical depth in the case-1 waters was found as deep as 39.79 m (λ=475 nm), followed by intermediate water of 31.79 m (λ=475 nm), and in the case-2 waters of 16.08 m (λ=490 nm). Both Kd (490) in situ and modelled results showed a good correlation (r=0.83-0.84) and R2 values of 0.68-0.71.

Diurnal Variation of the Diffuse Attenuation Coefficient for Downwelling Irradiance at 490 nm in Coastal East China Sea

The diurnal variation of the diffuse attenuation coefficient for downwelling irradiance at 490 nm (Kd(490)) has complex characteristics in the coastal regions. However, owing to the scarcity of in situ data, our knowledge on the diurnal variation is inadequate. In this study, an optical-buoy dataset was used to investigate the diurnal variation of Kd(490) in the coastal East China Sea, and to evaluate the Kd(490) L2 products of geostationary ocean color imager (GOCI), as well as the performance of six empirical algorithms for Kd(490) estimation in the Case-2 water. The results of validation show that there was high uncertainty in GOCI L2 Kd(490), with mean absolute percentage errors (MAPEs) of 69.57% and 68.86% and root mean square errors (RMSEs) of 0.70 and 0.71 m−1 compared to buoy-measured Kd12(490) and Kd13(490), respectively. Meanwhile, with the coefficient of determination (R2) of 0.71, as well as the lowest MAPE of 27.31% and RMSE of 0.29 m−1, the new dual ratio algorithm (NDRA) performed the best in estimating Kd(490) in the target area, among the six algorithms. Further, four main types of Kd(490) diurnal variation were found from buoy data, showing different variabilities compared to the area closer to the shore. One typical diurnal variation pattern showed that Kd(490) decreased at flood tide and increased at ebb tide, which was confirmed by GOCI images through the use of NDRA. Hydrometeorological factors influencing the diurnal variations of Kd(490) were also studied. In addition to verifying the predominant impact of tide, we found that the dominant effect of tide and wind on the water column is intensifying sediment resuspension, and the change of sediment transport produced by them are secondary to it.

Dependence of the Photosynthetic Quantum Yield on Phytoplankton Light Absorption: Equations for Assessing Primary Production in the Black Sea

Purpose. Investigations were performed during a scientific cruise to characterize hydrophysical properties, chlorophyll a concentration, photosynthesis-irradiance curves, spectral light absorption coefficients by phytoplankton, and spectral quantum downwelling irradiance. From these results, the dependence of the photosynthetic quantum yield upon environmental factors was studied with the purpose of adapting an algorithm developed for the Baltic Sea so that it can be applied for the Black Sea. Methods and Results. Complex hydrophysical and biological studies were carried out at several depths within the euphotic zone. Spectral bio-optical parameters were measured in accordance with the latest NASA protocols (2018). Experiments to determine the photosynthesis-light relationship were performed under temperature and light conditions similar to those in situ. The quantum yield of photosynthesis was calculated from parameters of photosynthesis-light curves (photosynthesis efficiency, light saturation parameter) and the spectral light absorption coefficients by phytoplankton pigments. It was found out that the main photosynthetic characteristics of phytoplankton, including the maximum photosynthetic quantum yield and the fraction of phytoplankton absorption associated with photoprotective accessory pigments, varied with depth within the euphotic zone, due to phytoplankton acclimation to environment factors during the period of seasonal stratification. The relationship between the photosynthetic quantum yield and the quanta absorbed by photosynthetically active phytoplankton pigments was revealed. The results of this research made it possible to build on the approach developed for other regions and modify the equation for calculating the quantum yield to apply specifically for environmental conditions in the Black Sea. Conclusions. For the first time, comprehensive studies carried out in the Black Sea, including measurements of the photosynthesis-light dependence, spectral light absorption coefficients by phytoplankton and spectral downwelling irradiance as a function of optical depths within the euphotic zone, made it possible to reveal the equation for calculating photosynthetic quantum yield. This new equation can be applied for calculating primary production of the Black Sea using a spectral approach, based both on the results of in situ measurements and remote sensing data.

Dependence of the Photosynthesis Quantum Yield on Phytoplankton Light Absorption: Equations for Assessing Primary Production in the Black Sea

Purpose. Based on the results of the investigations that were performed during the scientific cruise and included the water hydrophysical characteristics, the chlorophyll a concentration, the photosynthesis-light dependences, the spectral light absorption coefficients by phytoplankton, and the spectral quantum downwelling irradiance, the dependence of the photosynthesis quantum yield upon the environmental factors was studied with the purpose of adaptation of the developed for the Baltic Sea approach for assessing the photosynthesis quantum yield, to the Black Sea. Methods and Results. Complex hydrophysical and biological studies were carried out at several depths within the photosynthesis zone. Spectral bio-optical parameters were measured in accordance with the modern NASA protocol (2018). The experiments on studying the photosynthesis-light relationship were performed under the temperature and light conditions close to the in situ ones. The quantum yield of photosynthesis was calculated based on the parameters of photosynthesis-light dependences (photosynthesis efficiency, light saturation parameter) and the spectral light absorption coefficients by phytoplankton pigments. It was found out that the main photosynthetic characteristics of phytoplankton including the photosynthesis maximum quantum yield and the portion of photoprotective accessory pigments in the total light absorption by phytoplankton varied with depth within the euphotic zone due to phytoplankton adaptation to the environment factors during the period of water seasonal stratification. The relationship between the photosynthesis quantum yield and the number of solar energy quanta absorbed by the photosynthetically active phytoplankton pigments was revealed. The results of the performed research allowed for modifying the equation for calculating the quantum yield for the Black Sea environment conditions according to the approach developed for the other water areas. Conclusions. For the first time, comprehensive studies carried out in the Black Sea and including the measurements of the photosynthesis-light dependences, the spectral light absorption coefficients by phytoplankton and spectral downwelling irradiance at particular optical depths within the euphotic zone enabled to reveal the equation for calculating the photosynthesis quantum yield, which could be applied for calculating primary production of the Black Sea using the spectral approach based both on the results of in situ measurements and the remote sensing data.

Example of Monte Carlo Method Uncertainty Evaluation for Above-Water Ocean Colour Radiometry

We describe a method to evaluate an uncertainly budget for the in situ Ocean Colour Radiometric measurements. A Monte Carlo approach is chosen to propagate the measurement uncertainty inputs through the measurements model. The measurement model is designed to address instrument characteristics and uncertainty associated with them. We present the results for a particular example when the radiometers were fully characterised and then use the same data to show a case when such characterisation is missing. This, depending on the measurement and the wavelength, can increase the uncertainty value significantly; for example, the downwelling irradiance at 442.5 nm with fully characterised instruments can reach uncertainty values of 1%, but for the instruments without such characterisation, that value could increase to almost 7%. The uncertainty values presented in this paper are not final, as some of the environmental contributors were not fully evaluated. The main conclusion of this work are the significance of thoughtful instrument characterisation and correction for the most significant uncertainty contributions in order to achieve a lower measurements uncertainty value.

A Review of Protocols for Fiducial Reference Measurements of Downwelling Irradiance for the Validation of Satellite Remote Sensing Data over Water

This paper reviews the state of the art of protocols for the measurement of downwelling irradiance in the context of Fiducial Reference Measurements (FRM) of water reflectance for satellite validation. The measurement of water reflectance requires the measurement of water-leaving radiance and downwelling irradiance just above water. For the latter, there are four generic families of method, using: (1) an above-water upward-pointing irradiance sensor; (2) an above-water downward-pointing radiance sensor and a reflective plaque; (3) a Sun-pointing radiance sensor (sunphotometer); or (4) an underwater upward-pointing irradiance sensor deployed at different depths. Each method—except for the fourth, which is considered obsolete for the measurement of above-water downwelling irradiance—is described generically in the FRM context with reference to the measurement equation, documented implementations, and the intra-method diversity of deployment platform and practice. Ideal measurement conditions are stated, practical recommendations are provided on best practice, and guidelines for estimating the measurement uncertainty are provided for each protocol-related component of the measurement uncertainty budget. The state of the art for the measurement of downwelling irradiance is summarized, future perspectives are outlined, and key debates such as the use of reflectance plaques with calibrated or uncalibrated radiometers are presented. This review is based on the practice and studies of the aquatic optics community and the validation of water reflectance, but is also relevant to land radiation monitoring and the validation of satellite-derived land surface reflectance.

PENGUKURAN KOEFISIEN ATENUASI DAN HUBUNGANNYA DENGAN KUALITAS AIR DI PERAIRAN KELURAHAN PULAU PANGGANG

Koefisien atenuasi merupakan gambaran seberapa besar cahaya datang berkurang atau hilang dibandingkan dengan energi cahaya datang di permukaan. Pengurangan energi cahaya dikarenakan adanya proses absorpsi dan hamburan oleh kolom air dan materi yang terkandung di dalamnya seperti fitoplankton, padatan tersuspensi dan colored dissolved organic matter. Kuantitas cahaya yang mengalami atenuasi setara dengan jumlah cahaya yang diabsorpsi dan dihamburkan. Penelitian ini bertujuan untuk menganalisis hubungan antara koefisien atenuasi dengan kualitas air, serta mengkaji karakteristik optik perairan Kelurahan Pulau Panggang. Pengukuran spektral menggunakan TriOSRamses yang memiliki sensor irradiance dengan panjang gelombang antara 320 nm sampai 950 nm dan rentang kanal 3,3 nm. Perhitungan koefisien atenuasi (Kd) berdasarkan perubahan downwelling irradiance pada dua kedalaman berbeda. Korelasi Pearson digunakan untuk mengetahui hubungan antara Kd dengan kualitas air. Berdasarkan rentang panjang gelombang, Kd dibagi menjadi 4 yaitu Kd PAR, Kd biru, Kd hijau dan Kd merah. Kd biru dan Kd hijau memiliki hubungan paling erat dengan kecerahan sebesar 0,5406 dan 0,3990 serta bersifat negatif, sedangkan Kd PAR dan Kd merah paling erat hubungannya dengan muatan padatan tersuspensi sebesar 0,4015 dan 0,4073 dan bersifat positif. Perairan Kelurahan Pulau Panggang merupakan perairan turbid dengan nilai Kd PAR > 0,115 m-1.